Aluminium ion doping mechanism of lithium thiophosphate based solid electrolytes revealed with solid-state NMR

We investigate the impact of Al incorporation on the structure and dynamics of Al-doped lithium thiophosphates (Li3-3xAlxPS4) based on beta-Li3PS4. Al-27 and Li-6 magic-angle spinning NMR spectra confirm that Al3+ ions occupy octahedral sites in the structure. Quantitative analyses of Al-27 NMR spectra show that the maximum Al incorporation is x = 0.06 in Li3-3xAlxPS4. The ionic conductivity of beta-Li3PS4 is enhanced by over a factor 3 due to Al incorporation. Further increase of the Al doping level leads to the formation of a more complicated material consisting of multiple crystalline and distorted phases as indicated by P-31 NMR spectra and powder X-ray diffraction. Consequently, novel Li ion diffusion pathways develop leading to a very high ionic conductivity at room temperature. NMR relaxometry shows that the activation barrier for long-range Li ion diffusion in beta-Li3PS4 hardly changes upon Al incorporation, but the onset temperature for motional narrowing comes down significantly due to Al doping. The activation barrier in the subsequently formed multiphase material decreases significantly, however, indicating a different more efficient Li ion conduction pathway.

Automated summary

We investigated the impact of Al incorporation on the structure and dynamics of Al-doped lithium thiophosphates (Li3-3xAlxPS4) based on beta-Li3PS4. The results showed that Al3+ ions occupied octahedral sites in the structure and the maximum Al incorporation was x=0.06 in Li3-3xAlxPS4. The ionic conductivity of beta-Li3PS4 was significantly enhanced by over three times due to Al incorporation. Further increase of the Al doping level led to the formation of a more complicated material with multiple crystalline and distorted phases, resulting in a high ionic conductivity at room temperature.