Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 21, Issue 7, Pages 1384-1388Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ob02251f
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A palladium-catalysed carbon-carbon bond-forming reaction using organoammonium salts and carboxylic acids was developed. Various carboxylic acids, including polyfluoroaromatic carboxylic acids, propiolic acids, and alpha-cyano benzyl carboxylic acid, reacted smoothly with benzyl ammonium salts to give the desired coupling products in good-to-excellent yields.
A palladium-catalysed carbon-carbon bond-forming reaction via deaminative/decarboxylative cross-coupling of organoammonium salts with carboxylic acids was developed. Under the reaction conditions, polyfluoroaromatic carboxylic acids, propiolic acids and alpha-cyano benzyl carboxylic acid reacted smoothly with benzyl ammonium salts to produce the corresponding carbon-carbon coupling products in good-to-excellent yields.
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