Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 120, Issue 27, Pages 6890-6896Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcb.6b05404
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Funding
- National Natural Science Foundation of China [21274061, 21474050]
- Program for Changjiang Scholars and Innovative Research Team in University
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Creativity Plan for Ph.D. Candidates in the Common Universities
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We developed a linear combination of two Flory's melting point theories, one for stretched and the other for solution polymers, to predict the melting point of stretched solution polymers. The dependences of the melting strains on varying temperatures, polymer volume fractions, and solvent qualities were verified by the onset strains of crystallization in our dynamic Monte Carlo simulations of stretched solution polymers under a constant strain rate. In addition, owing to phase separation before crystallization in a poor solvent, calibration of polymer concentration to the polymer-rich phase appears necessary for the verification. Our results set up a preliminary thermodynamic background for the investigation of the multi component effect on strain-induced crystallization of polymers in rubbers and gels as well as on shear-induced crystallization of polymers in solutions and blends.
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