Journal
NEW JOURNAL OF CHEMISTRY
Volume 47, Issue 1, Pages 41-45Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nj03473e
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Categories
Funding
- NSFC
- Strategic Priority Research Program of the Chinese Academy of Sciences
- Fujian Natural Science Foundation
- [22071242]
- [21871260]
- [XDB20000000]
- [2018J05035]
- [2021J01522]
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A catalytic method has been developed for the two-carbon expansion of five-membered beta-ketoesters to afford seven-membered carbon rings, tolerating various alkynyl 1,2-diketones, common ynones, and alkynyl ketoesters to generate products with multiple functional groups under mild and environmentally benign conditions.
A catalytic method affording seven-membered carbon rings via two-carbon expansion of five-membered beta-ketoesters has been developed. This method tolerates various alkynyl 1,2-diketones, common ynones, and alkynyl ketoesters, and affords the corresponding products with multiple functional groups under mild and environmentally benign conditions.
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