Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 120, Issue 29, Pages 7053-7061Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcb.6b03694
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Funding
- Associated Laboratory for Sustainable Chemistry, Clean Processes and Technologies, LAQV
- national funds from FCT/MEC [UID/QUI/50006/2013]
- ERDF under the PT2020 Partnership Agreement [POCI-01-0145-FEDER-007265]
- Fundacao para a Ciencia e a Tecnologia [RECI/BBB-BQB/0230/2012]
- FCT/MEC [SFRH/BPD/72652/2010, SFRH/BPD/84805/2012]
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The equilibrium between 6- and 8-bromo-apigeninidin is quantitatively displaced toward the formation of the former in the presence of cucurbit[7]uril because of the selective recognition of the 6-bromo isomer by the host. This phenomenon permits us to conceive a unidirectional multistate switch addressed with host guest inputs and enables the reversible activation and deactivation of the 6-/8-bromo-apigeninidin dynamic molecular multistate through coupled host-guest and pH inputs.
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