4.8 Article

Leveraging Pd(100)/SnO2 interfaces for highly efficient electrochemical formic acid oxidation

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Engineering Ir Atomic Configuration for Switching the Pathway of Formic Acid Electrooxidation Reaction

Tao Shen et al.

Summary: The study found that by controlling the atomic configuration of iridium, the performance of formic acid oxidation reaction can be improved, and the transition from CO intermediate to direct CO2 formation can be achieved by constructing ordered intermetallics, enhancing both activity and stability.

ADVANCED FUNCTIONAL MATERIALS (2022)

Review Chemistry, Inorganic & Nuclear

Pd-based intermetallic nanocrystals: From precise synthesis to electrocatalytic applications in fuel cells

Sumei Han et al.

Summary: Pd-based intermetallic nanocrystals (INCs) have gained attention as electrocatalysts for fuel cells, showing outstanding catalytic activity and high stability. Research focuses on synthetic methods, morphology control, and applications in electrocatalytic reactions, with strategies to improve performance discussed.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Chemistry, Physical

Role of the Secondary Metal in Ordered and Disordered Pt-M Intermetallic Nanoparticles: An Example of Pt3Sn Nanocubes for the Electrocatalytic Methanol Oxidation

Hsiang-Sheng Chen et al.

Summary: The study found that in Pt3Sn catalysts, 60% ordered nanocubes exhibit higher activity compared to 95% ordered nanocubes, as the Sn atoms in the 60% ordered nanocubes are more easily oxidized to Sn4+, leading to better oxidation efficiency. This highlights the importance of controlling the environment and neighboring atoms in catalyst design for intermetallic Pt-M electrocatalysts.

ACS CATALYSIS (2021)

Review Chemistry, Applied

Copper-comprising nanocrystals as well-defined electrocatalysts to advance electrochemical CO2 reduction

Jianfeng Huang et al.

Summary: Copper-based electrocatalysts have garnered significant attention in the field of electrochemical CO2 reduction due to their ability to produce high value-added multicarbon products. Various Cu-comprising nanocrystals show better catalytic properties and enable in-depth mechanistic studies. Future research should focus on expanding catalyst varieties, managing active sites effectively, and addressing challenges in industrial applications.

JOURNAL OF ENERGY CHEMISTRY (2021)

Article Chemistry, Physical

Boosting electrocatalytic oxidation of formic acid on SnO2-decorated Pd nanosheets

Ya-Wei Zhou et al.

Summary: In this study, Pd nanosheets decorated with SnO2 nanoflakes (Pd@SnO2-NSs) were designed as a composite catalyst for formic acid electro-oxidation, showing superior performance compared to pristine Pd nanosheets (Pd-NSs). In situ attenuated total reflection infrared (ATR-IR) spectroscopic results suggest a promoted formate pathway on the Pd@SnO2-NSs with suppressed accumulation of CO poisoning species. DFT calculations further indicate that the Pd (111) surface modified with SnO2 has lower energy barriers for key reactions in formic acid electro-oxidation.

JOURNAL OF CATALYSIS (2021)

Article Chemistry, Applied

Easy preparation of multifunctional ternary PdNiP/C catalysts toward enhanced small organic molecule electro-oxidation and hydrogen evolution reactions

Zhipeng Yu et al.

Summary: A simple phosphorization treatment can greatly enhance the electrocatalytic performance of palladium-nickel catalysts in direct liquid fuel cells and water electrolyzers, showing substantial promise for large-scale applications.

JOURNAL OF ENERGY CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Rich grain boundaries endow networked PdSn nanowires with superior catalytic properties for alcohol oxidation

Huaming You et al.

Summary: Networked nanowire-structured PdSn catalysts exhibit excellent catalytic activity and stability for alcohol oxidation reactions, showing significantly improved performance compared to traditional Pd/C catalysts. The introduction of Sn promotes oxidation of intermediates, while the optimal NNW structure provides rich grain boundaries and active sites for enhanced catalytic performance.

NANOSCALE (2021)

Review Chemistry, Multidisciplinary

Recent advances in formic acid electro-oxidation: from the fundamental mechanism to electrocatalysts

Zhongying Fang et al.

Summary: Research on direct formic acid fuel cells is crucial for understanding the mechanism of formic acid oxidation reaction and designing high-performance electrocatalysts. This review briefly outlines the recent progress in this field, which has played a significant role in advancing the field.

NANOSCALE ADVANCES (2021)

Article Chemistry, Physical

Enhanced Formic Acid Oxidation over SnO2-decorated Pd Nanocubes

Clara Rettenmaier et al.

ACS CATALYSIS (2020)

Article Chemistry, Physical

Pd Nanocrystals with Continuously Tunable High-Index Facets as a Model Nanocatalyst

Neng-Fei Yu et al.

ACS CATALYSIS (2019)

Article Chemistry, Physical

Ligand Effect of Shape-Controlled beta-Palladium Hydride Nanocrystals on Liquid-Fuel Oxidation Reactions

Mrinal Kanti Kabiraz et al.

CHEMISTRY OF MATERIALS (2019)

Article Chemistry, Physical

Dual-Facet Mechanism in Copper Nanocubes for Electrochemical CO2 Reduction into Ethylene

Giulia Mangione et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2019)

Article Chemistry, Multidisciplinary

Trimetallic Synergy in Intermetallic PtSnBi Nanoplates Boosts Formic Acid Oxidation

Shuiping Luo et al.

ADVANCED MATERIALS (2019)

Article Chemistry, Physical

Metal-Oxide Interfaces for Selective Electrochemical C-C Coupling Reactions

Chan Woo Lee et al.

ACS ENERGY LETTERS (2019)

Article Chemistry, Multidisciplinary

Pt-Richcore/Sn-Richsubsurface/Ptskin Nanocubes As Highly Active and Stable Electrocatalysts for the Ethanol Oxidation Reaction

Ruben Rizo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Multidisciplinary Sciences

Potential-induced nanoclustering of metallic catalysts during electrochemical CO2 reduction

Jianfeng Huang et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Multidisciplinary

Stabilizing CuPd Nanoparticles via CuPd Coupling to WO2.72 Nanorods in Electrochemical Oxidation of Formic Acid

Zheng Xi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Physical

Counting electrons on supported nanoparticles

Yaroslava Lykhach et al.

NATURE MATERIALS (2016)

Article Chemistry, Multidisciplinary

A Pd/C-CeO2 Anode Catalyst for High-Performance Platinum-Free Anion Exchange Membrane Fuel Cells

Hamish A. Miller et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Multidisciplinary Sciences

Photochemical route for synthesizing atomically dispersed palladium catalysts

Pengxin Liu et al.

SCIENCE (2016)

Article Multidisciplinary Sciences

Microbial synthesis of highly dispersed PdAu alloy for enhanced electrocatalysis

Jiawei Liu et al.

SCIENCE ADVANCES (2016)

Article Chemistry, Physical

Understanding the Effect of the Adatoms in the Formic Acid Oxidation Mechanism on Pt(111) Electrodes

Adolfo Ferre-Vilaplana et al.

ACS CATALYSIS (2015)

Article Chemistry, Multidisciplinary

An Effective Pd-Ni2P/C Anode Catalyst for Direct Formic Acid Fuel Cells

Jinfa Chang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Multidisciplinary

Raisin Bun-Like Nanocomposites of Palladium Clusters and Porphyrin for Superior Formic Acid Oxidation

Xiuxin Wang et al.

ADVANCED MATERIALS (2013)

Review Biotechnology & Applied Microbiology

Catalysis on faceted noble-metal nanocrystals: both shape and size matter

Shuifen Xie et al.

CURRENT OPINION IN CHEMICAL ENGINEERING (2013)

Article Chemistry, Multidisciplinary

Poisoning effect diminished on a novel PdHoOx/C catalyst for the electrooxidation of formic acid

Ligang Feng et al.

CHEMICAL COMMUNICATIONS (2012)

Article Chemistry, Physical

SnO2 nanospheres supported Pd catalyst with enhanced performance for formic acid oxidation

Haiting Lu et al.

JOURNAL OF POWER SOURCES (2012)

Article Chemistry, Physical

Shape-dependent electrocatalysis: formic acid electrooxidation on cubic Pd nanoparticles

Francisco J. Vidal-Iglesias et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2012)

Article Chemistry, Physical

Mechanism of the Electrocatalytic Oxidation of Formic Acid on Metals

Angel Cuesta et al.

ACS CATALYSIS (2012)

Proceedings Paper Engineering, Chemical

Overview on Direct Formic Acid Fuel Cells (DFAFCs) as an Energy Sources

N. M. Aslam et al.

2ND INTERNATIONAL CONFERENCE ON CHEMISTRY AND CHEMICAL PROCESS (ICCCP 2012) (2012)

Article Chemistry, Physical

Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles

Georgi N. Vayssilov et al.

NATURE MATERIALS (2011)

Article Electrochemistry

CO tolerance and catalytic activity of Pt/Sn/SnO2 nanowires loaded on a carbon paper

Wen-Zhong Hung et al.

ELECTROCHIMICA ACTA (2010)

Article Multidisciplinary Sciences

Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding

Jason A. Farmer et al.

SCIENCE (2010)

Article Chemistry, Physical

Understanding underlying processes in formic acid fuel cells

Sunghyun Uhm et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2009)

Article Chemistry, Physical

Particle size effects in Pd-catalyzed electrooxidation of formic acid

Weijiang Zhou et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2008)

Review Chemistry, Physical

Recent advances in direct formic acid fuel cells (DFAFC)

Xingwen Yu et al.

JOURNAL OF POWER SOURCES (2008)

Article Chemistry, Physical

Formic acid electrooxidation on Pd in acidic solutions studied by surface-enhanced infrared absorption spectroscopy

Hiroto Miyake et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2008)

Article Chemistry, Physical

Structural effects of electrochemical oxidation of formic acid on single crystal electrodes of palladium

N Hoshi et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2006)