Journal
MOLECULES
Volume 28, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/molecules28010006
Keywords
camphene; hydration; SBA-15; heteropolyacids; sulfonic acid groups
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Camphene was hydtated over SBA-15 supported with sulfonic acid and tungstophosphoric acid. Isoborneol was the main product, with camphene hydrate and borneol as byproducts. The catalytic activity increased with the amount of tungstophosforic acid immobilized until reaching a maximum, but decreased with further increase. The catalytic stability of PW4-SBA-15-SO3H was observed during consecutive batch runs.
The hydration of camphene was carried out over SBA-15 with sulfonic acid groups and tungstophosphoric acid at 50 degrees C. The main product of camphene hydration was isoborneol, with camphene hydrate and borneol as byproducts. The catalytic activity increased with the amount of tungstophosforic acid (PW) immobilized on the silica support until a maximum, which was obtained with the PW4-SBA-15-SO3H material (16.4 wt.%). When the amount of PW immobilized on SBA-15 increased (PW5-SBA-15-SO3H, 21.2 wt.%), the catalytic activity decreased. The catalytic activity of PW4-SBA-15-SO3H increased with the water content of the solvent, until a maximum was reached with 50% water. With higher water concentrations, a decrease in the catalytic activity was observed. The selectivity to isoborneol was 90% at 99% camphene conversion in the presence of the PW4-SBA-15-SO3H catalyst. The catalytic stability of the PW4-SBA-15-SO3H material during camphene hydration was studied by performing consecutive batch runs with the same catalyst sample. After the third run, a trend towards stabilized catalytic activity was observed. A kinetic model is also proposed.
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