Journal
MOLECULES
Volume 27, Issue 24, Pages -Publisher
MDPI
DOI: 10.3390/molecules27248722
Keywords
porous organic polymers (POPs); triazaisotruxene; triazatruxene; crosslinking; iodine capture
Funding
- NSFC
- Natural Science Foundation of Fujian Province
- Science and technology project of Minjiang University
- [22071024]
- [22271047]
- [2021J06020]
- [2022J011121]
- [MJY21027]
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A new triazaisotruxene-based porous organic polymer with good thermal stability was designed and synthesized as a promising adsorbent for iodine in various solutions.
A new triazaisotruxene-based porous organic polymer (POP) was designed and successfully synthesized by a FeCl3-promoted crosslinking reaction. As a result of its porosity and good thermal stability, the designed POP can be utilized as a promising adsorbent for iodine, not only in the gaseous phase, but also in organic and aqueous solutions. Compared to its triazatruxene (TN) analogue, the ITN-based POP shows equal iodine uptake in the gaseous phase and in hexane solution, and better uptake in aqueous solution.
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