Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY
Volume 158, Issue -, Pages 235-242Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotobiol.2016.03.010
Keywords
Prunus avium; N-doped carbon dot; Fluorescence; Fe3+ sensor; Cytotoxicity; Bio-imaging
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Funding
- Yeungnam University [214A345036]
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This paper reports turn-off fluorescence sensor for Fe3+ ion in water using fluorescent N-doped carbon dots as a probe. A simple and efficient hydrothermal carbonization of Prunus avium fruit extract for the synthesis of fluorescent nitrogen-doped carbon dots (N-CDs) is described. This green approach proceeds quickly and provides good quality N-CDs. The mean size of synthesized N-CDs was approximately 7 nm calculated from the high resolution transmission electron microscopic images. X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy revealed the presence of -OH,-NH2,-COOH, and -CO functional groups over the surface of CDs. The N-CDs showed excellent fluorescent properties, and emitted blue fluorescence at 411 nm upon excitation at 310 nm. The calculated quantum yield of the synthesized N-CDs is 13% against quinine sulfate as a reference fluorophore. The synthesized N-CDs were used as a fluorescent probe towards the selective and sensitive detection of biologically important Fe3+ ions in water by fluorescence spectroscopy and for bio-imaging of MDA-MB-231 cells. The limit of detection (LOD) and the Stern-Volmer quenching constant for the synthesized N-CDs were 0.96 mu M and 2.0958 x 10(3) M of Fe3+ ions. The green synthesized N-CDs are efficiently used as a promising candidate for the detection of Fe3+ ions and bio-imaging. (C) 2016 Elsevier B.V. All rights reserved.
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