Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 330, Issue -, Pages 134-139Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2016.07.033
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Funding
- National Science Centre Project [2013/11/B/ST4/00500]
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UV photochemistry of H2O2 isolated in solid nitrogen at 15 K has been studied experimentally by FTIR matrix isolation technique and theoretically using DFT and MP2 methods. The major photoproducts were identified as (i) nitrous oxide and N2O center dot center dot center dot H2O complex and (ii) free and complexed to N2O hydroxyl radicals. Except for the OH radicals all observed species are unique and characteristic for H2O2 photolysis in solid nitrogen. The identities of the products have been confirmed by comparison with results of quantum chemical calculations, and reference to the spectral data of related molecules. Differences in the photolysis course upon irradiation at 230 and 212 nm are discussed. (C) 2016 Elsevier B.V. All rights reserved.
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