Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 324, Issue -, Pages 106-116Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2016.03.015
Keywords
Dyad; Hg2+; Cu2+; DL cell; Crossword puzzle
Categories
Funding
- Council of Scientific and Industrial Research (CSIR), New Delhi [CSIR 02 (0199/14/EMR-II)]
Ask authors/readers for more resources
An intramolecular charge transfer (ICT) based fluorescence turn-on ratiometric probe BTIM (D-pi-A type) has been designed and synthesized by bridging imidazole (donor, D) and benzothiazole (acceptor, A) moieties through a thiophene ring. The photophysical behavior of probe and its affinity toward metal ions has been investigated in HEPES buffer, protein medium and live cells. The probe upon interaction with different cations has shown high sensitivity and selectively for Hg2+ and Cu2+ ions through fluorescence turn-On and turn-Off response respectively along with naked-eye sensitive color changes. The significant change in photophysical behavior of the probe is attributable to restricted ICY upon complexation between probe and metal ions in a 1:1 stoichiometry. The mechanism of interaction has been established by H-1 NMR, FT-IR, ESI-M Sand DFT calculation methods. The probe has shown excellent cell permeability and successfully detected Hg2+ and Cu2+ ions in Dalton's Lymphoma (DL) cells, in protein medium (BSA), in real water samples and on test paper strips. Moreover, the optical behavior of probe has been explored as a Coding-Decoding Fluorescent Blue Security Ink on silica gel surface and in construction of crossword puzzle with specific security code 'HCO'. (C) 2016 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available