4.6 Article

A flexibly hierarchical porous polydimethylsiloxane film for Passive daytime radiative cooling

Journal

MATERIALS LETTERS
Volume 331, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2022.133512

Keywords

Polymers; Porous materials; Phase-separation; Radiative cooling

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Passive daytime radiative cooling technology cools objects by reflecting sunlight and radiating heat into outer space, without requiring additional energy. A flexibly hierarchical porous PDMS radiative cooling film was fabricated, which has high emissivity and reflectance, resulting in a significant temperature drop.
Passive daytime radiative cooling (PDRC) is a technology without requiring additional energy that cools objects by reflecting sunlight and radiating heat into outer space. However, the design process of PDRC films is relatively complicated or costly, which is not conducive to large-scale fabrication. For this, we fabricated a flexibly hier-archical porous polydimethylsiloxane (PDMS) radiative cooling film, which is simple and fast to fabricate and can be used for efficient large-scale production. It can reach the average emissivity of 0.95 in the transparent atmospheric window (8-13 mu m). The average reflectance is above 0.7 in the solar wavelength band (0.3-2.5 mu m), which is nearly 9 times of the non-porous structure. Thus, the porous PDMS films realize excellent sub-ambient temperature drop of 14.9 degrees C at the solar intensity of 910 W/m2.

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