4.8 Article

Robust Crystalline Hybrid Solid with Multiple Channels Showing High Anhydrous Proton Conductivity and a Wide Performance Temperature Range

Journal

ADVANCED MATERIALS
Volume 28, Issue 8, Pages 1663-1667

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201504591

Keywords

anhydrous proton conductors; open-framework chalcogenides; proton conductivity; hybrid solids

Funding

  1. Priority Academic Program Development of Jiangsu Higher Education Institutions
  2. Special Research Fund for the Doctoral Program of Higher Education
  3. National Nature Science Foundation of China [20123221110013, 21271103]

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A proton conductor displaying high anhydrous proton conductivity (approximate to 10(-2) S cm(-1)) and good performance over a broad temperature range is presented. This hybrid material is produced via doping HCl into open-framework chalcogenide(C2N2H10)(C2N2H9)(2)Cu-8 Sn3S12, and has cubopolyhedral cavities and multiple channels. [GRAPHICS] .

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