Surprising Hydrophobic Polymer Surface with a High Content of Hydrophilic Polar Groups

The wetting property of a solid surface has been a hotspot for centuries, and many studies suggest that the hydrophobicity is highly related to the polar components. However, the underlying mechanism of polar moieties on the hydrophobicity remains unclear. Here, we tailor the surface polar moieties of epoxy resin (EP) by ozone modification and assess their wetting properties. Our results show that, for the modified EP with more (60.54%) polar moieties, the polar effect on hydrophobicity cannot be empirically observed. To reveal the underlying mechanism, the absorption parameters, including equili-brium distance, adsorption radius, and effective adsorption sites for water on EP before and after ozone treatment, are calculated on the basis of molecular simulations. After ozone modification, the equilibrium distance (from 1.95 to 1.70 angstrom), adsorption radius (from 3.80 to 4.50 angstrom), and effective adsorption sites (from 1 to 2) change slightly and the EP surface remains hydrophobic, although the polar groups significantly increase. Therefore, it is concluded that the wetting properties of solid surfaces are dominated by the equilibrium distance, adsorption radius, and effective adsorption sites for water on solids, and the nonlinear relationship between polar groups and hydrophilicity is clarified.

Automated summary

This study investigates the influence mechanism of polar groups on hydrophobicity by modifying the surface polar moieties of epoxy resin. The results show that even with a significant increase in polar groups, the modified epoxy resin surface remains hydrophobic. By calculating absorption parameters using molecular simulations, the study reveals the controlling factors of wetting properties on solid surfaces and clarifies the nonlinear relationship between polar groups and hydrophilicity.