Efficient photodegradation of methyl orange and bactericidal activity of Ag doped ZnO nanoparticles

In the present work, silver-doped ZnO (Ag-ZnO NPs) with different concentrations of silver ions (0.3, 0.5, 1.0 and 1.5 mol %) were synthesized by using a simple co-precipitation method. The Ag-ZnO NPs were primarily characterized by XRD, FT-IR, SEM, EDS, TEM, UV-Vis. DRS, PL and BET surface area. The XRD analysis of Ag-ZnO NPs shows a wurtzite structure and optimized Ag-ZnO NPs (1.0 mol %) exhibit a lower crystallite size of 15.96 nm than that of bare ZnO (19.07 nm). Optical study shows a decrease in band gap from 3.13 to 2.97 eV as the concentration of Ag ions increases from 0.3 to 1.5 mol%. TEM images reveal the spherical shape particle with sizes ranging between 10 and 15 nm. From the multipoint BET plot, the surface area of Ag-ZnO NPs found 38.06 m2/gwhich is higher than the ZnO NPs (34.48 m2/g). The photocatalytic study demonstrated that the Ag-ZnO NPs (1.0 mol %) has an excellent photodegradation efficiency of Methyl Orange (96.74%)with a 26% increment as compared to bare ZnO (70.47%). Furthermore, the bactericidal activity of Ag-ZnO NPs (1.0 mol %) was investigated against four different bacterial strains. The results explored that the Gram-negative bacteria (E. coli and P. vulgaris) are more sensitive than Gram-positive (S. aureus and B. cereus) to Ag-ZnO NPs. Overall, the anticipated material is economical and reusable for photodegradation and antibacterial activity.

Automated summary

Silver-doped ZnO nanoparticles (Ag-ZnO NPs) with different concentrations of silver ions were synthesized and characterized using various techniques. The optimized Ag-ZnO NPs exhibited a smaller crystallite size and a decreased band gap compared to bare ZnO. In addition, the Ag-ZnO NPs demonstrated enhanced photocatalytic efficiency and bactericidal activity, making them a promising and reusable material for degradation and antibacterial applications.