4.7 Article

Effect of Al4B2O9 and Al18B4O33 whiskers synthesized in situ on the evolution of microstructure and mechanical properties of white fused alumina and Cubitron glass-ceramic composites

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 43, Issue 6, Pages 2564-2577

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2022.12.062

Keywords

White fused alumina; Microcrystalline alumina; Glass-ceramic bond; Aluminum borate whiskers; Tensile strength

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This paper investigates the influence of in situ crystallization of aluminum borate whiskers on the microstructure and mechanical properties of electrocorundum and microcrystalline alumina glass-ceramic porous composites. The results show that the crystallization process varies in both composites, affecting their microstructure and mechanical properties. An increase in mechanical tensile strength of 36% was observed for both composites, with the highest tensile strength depending on the type of abrasive grain and the amount of whisker precursor added. Furthermore, a significant increase in Young's modulus values was observed for composites containing 40 wt% precursor: by 45% for electrocorundum and by 52% for microcrystalline alumina.
The present paper reports on the influence of in situ crystallization of aluminum borate whiskers on the evolution of the microstructure and mechanical properties of electrocorundum (white fused alumina) and microcrystalline alumina (Cubitron 321TM) glass-ceramic porous composites. The investigated composites were obtained by sintering the white fused alumina (WFA) and Cubitron 321TM abrasive grains, glass-ceramic bond and various amounts of precursor for whisker growth. The results showed that in the presented technology, the crystallization of the composite reinforcing phases proceeds differently in both types of composites, which affects their microstructure and mechanical properties. An increase in the mechanical tensile strength of 36% was observed for both types of composites; however, depending on the type of abrasive grain, the composites with the highest tensile strength differed in the amount of whisker precursor added. A significant increase in the Young's modulus values was also observed for composites containing 40 wt% precursor: by 45% for WFA and by 52% for Cubitron 321TM.

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