Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 316, Issue -, Pages -Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2022.123551
Keywords
Ammonium perchlorate; Metal-organic framework; Amino acid; Thermal decomposition
Funding
- Xianyang Normal University
- [XSYK20037]
- [2017072]
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Two copper metal-organic frameworks with L-serine Schiff base and L-tyrosine have been synthesized, and exhibit outstanding catalytic effects.
Two copper metal-organic frameworks (MOFs) have been synthesized using L-serine Schiff base (2-(2-oxhydryl-phenylmethanimine)-3-oxhydryl-propionic acid = H2pmpa) and L-tyrosine (L-Tyr). The new MOF {[Cu(pmpa)(H2O)]center dot H2O}n (1) and another MOF {Cu(L-Tyr)2}n (2) were prepared by a one-pot method, and indicate square-based pyramidal geometry. Both MOFs display outstanding catalytic effects for the thermal decomposition of ammonium perchlorate (AP) and hexogen (RDX).
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