4.8 Article

Mesoporous Metal-Organic Frameworks with Size-, Shape-, and Space-Distribution-Controlled Pore Structure

Journal

ADVANCED MATERIALS
Volume 27, Issue 18, Pages 2923-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201405752

Keywords

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Funding

  1. AcRF Tier 2 from Ministry of Education, Singapore [RG 17/12]
  2. Singapore National Research Foundation under the Campus for Research Excellence and Technological Enterprise Programmed Nanomaterials for Energy and Water Management
  3. Foundation for Distinguished Young Scholars of Jiangsu Province [BK20140044]

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Mesoporous Metal-organic frameworks (meso-MOFs) with size-, shape-, and space-distribution-controlled mesopores are obtained by a facile encapsulation and selective etching strategy of metal nanoparticles. Hierarchical or functionalized meso-MOFs are achieved by the above strategy. Interestingly, the functional meso-MOFs display higher catalytic activity originating from the mesopores existing in the MOFs, as well as good selectivity due to protection of the micro porous frameworks.

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