Influence of oxygen and nitrogen doping on the structure and magnetic properties of CoNi alloy: First principle calculations

We have studied the effects of oxygen and nitrogen doping as interstitial defects on the structure and magnetic properties of CoNi alloy using the first principle density functional theory, where we include the orbital-spin interaction in the calculations. Our calculations reveal that the CoNi:ONi in the L10-structure has a large enhancement in the saturation magnetization (Ms) and a small reduction in the magnetic crystalline anisotropy (MCA). For CoNi:OCo, we found a small reduction in Ms and MCA. However, for CoNi:NCo and CoNi:NNi there is always a reduction in Ms and MCA. Therefore, the first alloy could be suitable for permanent magnets. A detailed analysis of other parameters, such as the magnetic hardness parameter (kappa), optimum supercell parameters, anisotropy field (Ha), and formation energy (Efor) is presented. The interstitial oxygen doping enhances the magnetic properties.

Automated summary

In this study, we investigated the effects of oxygen and nitrogen doping on the magnetic properties of CoNi alloy using density functional theory. Our calculations revealed that CoNi:ONi alloy exhibited enhanced saturation magnetization and slightly reduced magnetic crystalline anisotropy, while CoNi:OCo alloy showed a small reduction in both parameters. On the other hand, CoNi:NCo and CoNi:NNi alloys consistently exhibited reductions in saturation magnetization and magnetic crystalline anisotropy. Therefore, CoNi:ONi alloy could be suitable for permanent magnets.