4.5 Article

Mo-Ag nanocomposite catalysts for the oxygen evolution reaction

Journal

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2022.111041

Keywords

Mo-Ag nanocomposite Powders; High energy ball milling; Electrochemical properties; Oxygen evolution reaction (OER); Water splitting

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In this study, Mo-Ag nanocomposites were prepared through high energy ball milling and reduction, and their electrochemical performance was evaluated. The results showed that longer milling time led to smaller particle and crystallite sizes, resulting in higher electrocatalytic activity. The Mo-Ag nanocomposites exhibited good electrochemical stability and catalytic activity in the oxygen evolution reaction.
Nanocomposite powders are interesting electrocatalysts for efficient water splitting in alkaline medium. In this work, Mo-Ag nanocomposites were prepared by high energy ball milling of (NH4)6Mo7O24.4H2O and AgNO3 precursors, with subsequent reduction in hydrogen atmosphere. High energy ball milling formed spheres composed of needle-like structures of different sizes. The particle size decreases with increasing the milling time from 20 h to 40 h, with the same trend observed for crystallite sizes. The electrochemical performance for the oxygen evolution reaction (OER) is assessed using linear sweep (LSV) and cyclic (CV) voltammetry, electro-chemical impedance spectroscopy (EIS), and chronopotentiometry (CP). The values of overpotential, Tafel slope, double layer capacitance (CDL) and turnover frequency (TOF) of samples milled for 20 h and 40 h are determined to be 350 and 330 mV vs. RHE, 84 and 75 mV dec- 1, 5.4 and 6.2 mF cm-2, 3.84 x 10-3 and 6.98 x 10-3 mol O2 s- 1 increased surface area dramatically boosts the electrochemical processes with adsorbed species. Chro-nopotentiometry measurements for 15 h reveal that electrodes exhibit acceptable short-term electrochemical stability. The overall results suggest that Mo-Ag nanocomposites are promising materials for the oxygen evo-lution reaction, being among the best Mo-based electrocatalysts reported in the literature. , respectively, which suggests an improved electrocatalytic activity for the sample milled for 40 h. The

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