Effective Hard-Sphere Repulsions between Oleate-Capped Colloidal Metal Oxide Nanocrystals

Nanocrystal interactions in solvent influence colloidal stability and dictate self-assembly outcomes. Small-angle X-ray scattering is used to study how dilute oleate-capped In2O3 nanocrystals with 7-19 nm core diameters interact when dispersed in a series of nonpolar solvents. Osmotic second virial coefficient analysis finds toluene-dispersed nanocrystals in this size range interact like effective hard spheres with diameters comprising the inorganic core and a ligand-solvent corona with a core-size independent thickness. Hard-sphere-like structure factors are similarly observed for nanocrystals with a 9.7 nm core diameter dispersed in all the solvents investigated. Nanocrystal hydrodynamic diameters from dynamic light scattering measurements correlate with thermodynamic diameters obtained from the osmotic second virial coefficient analysis for all samples. The ability to prepare nanoscale building blocks of different sizes, and dispersed in a variety of solvents, with effective hard-sphere repulsions provides a foundation for assembly, where secondary linking or depletant molecules can be deliberately added to customize interactions to form superstructures such as gel networks or superlattices.

Automated summary

The interactions between nanocrystals in solvents can affect their self-assembly behavior and colloidal stability. In this study, the interactions of oleate-capped In2O3 nanocrystals dispersed in nonpolar solvents were investigated using small-angle X-ray scattering and osmotic second virial coefficient analysis. The results demonstrated a correlation between the hydrodynamic diameter and thermodynamic diameter of the nanocrystals. This research provides a foundation for the customized assembly of nanoscale structures.