Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 435, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2022.114282
Keywords
Phenothiazine; Imine; Luminescence; Microwave-assisted synthesis; Dynamic character
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We report the synthesis and characterization of new PEGylated imine derivatives and investigate their photophysical behavior and dynamic character. The synthesized PEGylated imines show high quantum efficiency in solution and solid state, self-assembling behavior in ethanol, and the reversible switch of their emission color from green to yellow under the influence of external stimuli.
Herein we report the synthesis, characterization, photophysical behavior and dynamic character of new PEGy-lated imine derivatives. Two PEGylated phenothiazine aldehydes were synthetised and reacted with two amines bearing sulfonamide moiety via microwave assisted synthesis to yield four imine derivatives. The imines and the aldehydes precursors were structurally characterized by NMR and FTIR spectroscopy and their self-assembly behaviour was investigated by polarized light microscopy (POM) and dynamic light scattering (DLS). Photo-physical properties were investigated by UV-vis and photoluminescence spectroscopy and the quantum effi-ciency was determined using an integrating sphere. Dynamic character of the imine derivatives was explored by NMR and UV-vis spectroscopy in correlation with visual assessment of luminescence change. The new synthe-tized PEGylated imines showed solubility and stability in common organic solvents, high quantum efficiency in solution and solid state, self-assembling behaviour in ethanol, and dynamic character giving access to the reversible switch of their emission colour from green to yellow through shifting the imination equilibrium under the influence of external stimuli.
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