Journal
JOURNAL OF NATURAL PRODUCTS
Volume -, Issue -, Pages -Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jnatprod.2c00919
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This study presents the efficient syntheses of ugonstilbenes A, B, and C using the Horner-Wadsworth-Emmons reaction. The absolute configurations of ugonstilbenes A and C were determined to be R, while ugonstilbene B had the absolute configuration of 4aS,9aR. The synthesized compounds exhibited cytotoxic activities against specific human cancer cell lines.
This study describes the first and efficient syntheses of the naturally occurring ugonstilbenes A, B, and C. The stilbene skeleton was prepared using the Horner-Wadsworth-Emmons reaction. On the basis of their specific rotations, the absolute configurations of ugonstilbenes A and C were both determined to be R, while the absolute configuration of ugonstilbene B was determined as 4aS,9aR. The synthesized compounds showed cytotoxic activities against selected human cancer cell lines.
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