Optimizing impedance matching by a dual-carbon Co-regulation strategy of Co3O4@rGO/celery stalks derived carbon composites for excellent microwave absorption

Both macroscopic composition and microstructure should be considered for reasonable microwave absorbent designing. In this study, Co3O4@reduced graphene oxide (rG0)/Celery stalks derived carbon (CDC) was prepared by loading Co3O4 particles into rGO and biomass-derived carbon mixture through oxidation precipitation. By changing the mass ratio of rGO to CDC, the dielectric and impedance matching properties of the composites can be easily regulated. The RLmin value of Co3O4@rGO/CDC13 composite (weight ratio for rGO:CDC is 1:3) reaches -84.3 dB with a thickness of 4.6 mm, and the widest effective bandwidth can be obtained at 4.5 GHz with a matching thickness of 2.8 mm. The Co3O4@rGO/CDC13 composite with multiple components (Co3O4, CDC, rGO) and 3D net structure produces magnetic/dielectric loss combinations, interfacial polarization, and multiple reflections and scattering, and the CDC with half tube and half sheet structure is conducive to the optimization of impedance matching. The strategy of coregulating dielectric properties of materials with double carbon provides a novel pathway for the preparation of lightweight, low-cost, and high-performance absorbers. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Automated summary

Both macroscopic composition and microstructure should be considered for reasonable microwave absorbent designing. In this study, Co3O4@reduced graphene oxide (rGO)/Celery stalks derived carbon (CDC) composite was prepared, and the dielectric and impedance matching properties of the composites were successfully regulated by changing the mass ratio of rGO to CDC. The Co3O4@rGO/CDC composite with multiple components and 3D net structure showed promising magnetic/dielectric loss combinations, interfacial polarization, and multiple reflections and scattering, while the unique structure of CDC contributed to the optimization of impedance matching. The strategy of co-regulating dielectric properties of materials with double carbon provides a novel pathway for the preparation of lightweight, low-cost, and high-performance absorbers.