4.7 Article

Self-templated transformation of Co-ZIF-L into hierarchical porous CoS2/Co-Ni LDHs with improved electrochemical activities

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 629, Issue -, Pages 786-793

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2022.08.140

Keywords

ZIF-L; Co-Ni layered double hydroxide; Etching; Electrochemical performance

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By synthesizing CoS2/Co-Ni LDHs with rich hierarchical pores and uniformly distributed CoS2 nanoparticles, efficient mass diffusion and exposure of active sites are achieved, resulting in excellent specific capacitance and capacitance retention.
CoS2/Co-Ni layered double hydroxides (LDHs) with a rational tailored pore structure are developed by partial sulfurization of Co-ZIF-L and subsequent Ni2+ etching for the transformation of zeolitic imidazolate frameworks (ZIFs) to layered double hydroxides. The as-synthesized CoS2/Co-Ni LDHs maintain the leaf-like structure and have rich hierarchical pores. More importantly, CoS2 nanoparticles are uniformly embedded among Co-Ni LDH layers, facilitating mass diffusion and favorably exposing more active sites. Benefiting from these desirable compositional and structural features, a remarkable specific capacitance (capacity) of 1784 F/g (223 mAh/g) at 1 A/g is delivered by CoS2/Co-Ni LDHs. Furthermore, the as-assembled CoS2/Co-Ni LDH//activated carbon as the asymmetric supercapacitor device also exhibits a high energy density of 125 Wh/kg at a power density of 800 W/kg and a superb capacitance retention of 98 % after 5000 cycles, outperforming many Co-Ni LDH based electrode materials reported in the literature.(c) 2022 Elsevier Inc. All rights reserved.

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