4.7 Article

Optimization of acetamide based deep eutectic solvents with dual cations for high performance and low temperature-tolerant aqueous zinc ion batteries via tuning the ratio of co-solvents

Related references

Note: Only part of the references are listed.
Article Nanoscience & Nanotechnology

Intercalation of Zinc Monochloride Cations by Deep Eutectic Solvents for High-Performance Rechargeable Non-aqueous Zinc Ion Batteries

Shu-Chi Wu et al.

Summary: In this study, an alternative electrolyte system based on deep eutectic solvents (DESs) was developed to overcome the limitations of zinc ion batteries. Through in-depth characterization, the energy storage mechanism was discovered and high reversible capacity and long-term stability were achieved.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Engineering, Environmental

Engineering solid-electrolyte interface from aqueous deep-eutectic solvent to enhance the capacity and lifetime of self-assembled heterostructures of 1T-MoS2/graphene

Balaraman Vedhanarayanan et al.

Summary: This study presents a method to electrochemically deposit porous and flexible solid-electrolyte interface (SEI) coatings on active electrode materials using an aqueous deep-eutectic solvent. The uniform SEI film improves the specific capacity and rate capability of the composite electrode, while reducing electrolyte decomposition and charge transfer resistance during cycling. The novel approach is extrapolated as a general protocol to enhance the performance of lithium-ion batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

A tailor-made deep eutectic solvent for 2.2 V wide temperature-tolerant supercapacitors via optimization of N,N-dimethylformamide/water co-solvents

Yi-Ru Tsai et al.

Summary: The study improved the performance of deep eutectic solvent by adding co-solvents like water and DMF, which combined with PANI-rGO electrodes to form high-performance supercapacitors with high energy density and safety. The hybrid DES electrolyte exhibited good performance at low temperatures, opening a new avenue for sustainable and affordable energy storage devices.

JOURNAL OF POWER SOURCES (2022)

Article Chemistry, Physical

Graphene quantum dots enable dendrite-free zinc ion battery

Hao Zhang et al.

Summary: The practical application of aqueous Zn-ion batteries has been hindered by poor reversibility of Zn anode due to dendritic growth and interfacial parasitic reaction. A novel stable Zn anode was successfully designed by incorporating hydrophilic graphene quantum dots (GQDs), leading to improved performance and extended lifespan of Zn-ion batteries.

NANO ENERGY (2022)

Article Chemistry, Physical

Tailor-made organic polymers towards high voltage aqueous ammonium/potassium-ion asymmetric supercapacitors

K. C. Seetha Lakshmi et al.

Summary: Engineering polymers with electrochemical functionality is a contemporary research topic aimed at developing lightweight and low-cost energy storage devices. In this study, a pair of organic polymers were successfully synthesized by coupling redox-active moieties through different sulfide linkages, resulting in two distinct morphologies. These polymers were tested as electrode materials for supercapacitors in two different water-in-salt electrolytes, showing better performance in potassium acetate electrolyte for the polymer with monosulfide moieties compared to disulfide moieties.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

A 1.9-V all-organic battery-supercapacitor hybrid device with high rate capability and wide temperature tolerance in a metal-free water-in-salt electrolyte

Hsiang-Hsi Tsai et al.

Summary: This study demonstrates the performance of a composite hydrogel consisting of PTCDI and rGO as the anode for BSHs in NH4Ac electrolyte. The water-in-salt electrolyte exhibits a wide electrochemical stability window and high conductivity, leading to BSH devices with high energy density and excellent cycling stability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Physical

High-Yield Carbon Dots Interlayer for Ultra-Stable Zinc Batteries

Hao Zhang et al.

Summary: High yield carbon dots (CDs) with abundant polar functional groups are used to optimize the electrolyte/Zn interfaces, effectively preventing dendritic growth and parasitic reactions. The CDs also improve the reaction kinetics and lifespan of the Zn anode.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Physical

Stabilization Perspective on Metal Anodes for Aqueous Batteries

Huaping Wang et al.

Summary: Aqueous electrolyte-based batteries have advantages such as nonflammability, low cost, high power density, and environmental friendliness, but they suffer from low energy density due to the narrow stable electrochemical window of water and electrode materials with low capacity. Developing metal anodes with high specific capacity is seen as a promising solution to enhance the energy density of these batteries.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Water-in-salt electrolyte for safe and high-energy aqueous battery

Yuanhao Shen et al.

Summary: Water-in-salt electrolyte has improved the performance of aqueous lithium-ion batteries, but also increased the cost, hence aqueous sodium-ion batteries and zinc-based batteries show potential as alternatives.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Multidisciplinary

Water-Salt Oligomers Enable Supersoluble Electrolytes for High-Performance Aqueous Batteries

Shengying Cai et al.

Summary: This study reports a highly soluble ZnCl2/ZnBr2/Zn(OAc)(2) aqueous electrolyte, which breaks through the physical solubility limit by forming acetate-capped water-salt oligomers, enabling high-performance aqueous dual-ion batteries.

ADVANCED MATERIALS (2021)

Article Chemistry, Physical

Pseudocapacitive and battery-type organic polymer electrodes for a 1.9 V hybrid supercapacitor with a record concentration of ammonium acetate

K. C. Seetha Lakshmi et al.

Summary: Aqueous all-organic battery-supercapacitor hybrid devices are emerging as promising alternative energy storage systems due to easy processability, high tunability, cost-effectiveness, and recyclability. This study demonstrates an all-organic BSH device using a record concentration of ammonium acetate as a cheap and green electrolyte, showing good stability and cycling performance.

JOURNAL OF POWER SOURCES (2021)

Article Engineering, Environmental

Optimization of acetonitrile/water content in hybrid deep eutectic solvent for graphene/MoS2 hydrogel-based supercapacitors

Chia-Wei Lien et al.

Summary: In this study, a co-solvent-in-deep eutectic solvent system was developed by mixing water and acetonitrile with a typical DES electrolyte. The addition of co-solvents improved the conductivity and flame-retardant properties of the DES, leading to a wide electrochemical stability window. Furthermore, a hydrogel consisting of 1T-MoS2 and reduced graphene oxide was used as electrode materials for supercapacitors, demonstrating high energy density and capacitance retention after cycles.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

Design of a Solid Electrolyte Interphase for Aqueous Zn Batteries

Dan Li et al.

Summary: A low-concentration aqueous Zn(OTF)(2)-Zn(NO3)(2) electrolyte was designed to form a robust inorganic ZnF2-Zn-5(CO3)(2)(OH)(6)-organic bilayer SEI, allowing high Coulombic efficiency and energy density. The study achieved a high CE of 99.8% for 200 h in Ti parallel to Zn cells, and a high energy density of 168 Wh kg(-1) with 96.5% retention for 700 cycles in Zn parallel to MnO2 cells with a low Zn/MnO2 capacity ratio of 2:1.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Nanoscience & Nanotechnology

Fluorinated interphase enables reversible aqueous zinc battery chemistries

Longsheng Cao et al.

Summary: The study introduces an aqueous zinc battery with a solid-electrolyte interphase that enables excellent performance in various tests, demonstrating its potential for practical applications in energy storage.

NATURE NANOTECHNOLOGY (2021)

Review Chemistry, Physical

Design Strategies for High-Voltage Aqueous Batteries

Chongrui Dong et al.

Summary: This article summarizes recent progress on expanding the potential window of aqueous batteries, focusing on the design and modification of electrolytes, electrodes, and current collectors. Additionally, various alternative electrolytes are critically evaluated in terms of commercial prospects.

SMALL STRUCTURES (2021)

Article Chemistry, Multidisciplinary

Non-concentrated aqueous electrolytes with organic solvent additives for stable zinc batteries†‡

Yang Dong et al.

Summary: This study presents a non-concentrated aqueous electrolyte composed of 2m zinc trifluoromethanesulfonate and the organic dimethyl carbonate additive, which can stabilize the zinc electrochemistry and improve the coulombic efficiency of the zinc anode. Furthermore, this electrolyte can sustain stable operation of rechargeable aqueous zinc batteries when paired with various cathode materials. Rational electrolyte design with organic solvent additives could lead to the development of better aqueous batteries.

CHEMICAL SCIENCE (2021)

Article Nanoscience & Nanotechnology

Synergistic Effect of Cation and Anion for Low-Temperature Aqueous Zinc-Ion Battery

Tianjiang Sun et al.

Summary: This study demonstrates the synergistic effect of cation and anion to break the hydrogen-bonds network of water molecules, and proposes an aqueous-salt hydrates deep eutectic solvent with an ultralow freezing point. The electrolyte shows high ionic conductivity and low viscosity at low temperatures, leading to satisfactory performance of Zn||PTO and Zn||PNZ batteries. This work provides a unique perspective for designing anti-freezing aqueous electrolytes.

NANO-MICRO LETTERS (2021)

Article Chemistry, Multidisciplinary

A High-Potential Anion-Insertion Carbon Cathode for Aqueous Zinc Dual-Ion Battery

Qiubo Guo et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Review Chemistry, Physical

Energy Storage Chemistry in Aqueous Zinc Metal Batteries

Fang Wan et al.

ACS ENERGY LETTERS (2020)

Article Chemistry, Multidisciplinary

Solvation Structure Design for Aqueous Zn Metal Batteries

Longsheng Cao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Nanoscience & Nanotechnology

Electrolyte Effect on the Electrochemical Performance of Mild Aqueous Zinc-Electrolytic Manganese Dioxide Batteries

Huilin Pan et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Multidisciplinary Sciences

Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation

Huayu Qiu et al.

NATURE COMMUNICATIONS (2019)

Review Chemistry, Physical

A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries

Dinesh Selvakumaran et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Electrochemistry

Rechargeable Zinc-Ion Battery Based on Choline Chloride-Urea Deep Eutectic Solvent

Wathanyu Kao-ian et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

Article Chemistry, Physical

A low-cost water-in-salt electrolyte for a 2.3 V high-rate carbon-based supercapacitor

Xudong Bu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Multidisciplinary

Concentrated mixed cation acetate water-in-salt solutions as green and low-cost high voltage electrolytes for aqueous batteries

Maria R. Lukatskaya et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Physical

Highly reversible zinc metal anode for aqueous batteries

Fei Wang et al.

NATURE MATERIALS (2018)

Review Chemistry, Multidisciplinary

Inhibition of Zinc Dendrite Growth in Zinc-Based Batteries

Wenjing Lu et al.

CHEMSUSCHEM (2018)

Article Chemistry, Physical

Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3-x

Hyung-Seok Kim et al.

NATURE MATERIALS (2017)

Article Chemistry, Physical

Revisiting OPLS Force Field Parameters for Ionic Liquid Simulations

Brian Doherty et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2017)

Article Chemistry, Physical

Water-in-Salt Electrolyte Makes Aqueous Sodium-Ion Battery Safe, Green, and Long-Lasting

Liumin Suo et al.

ADVANCED ENERGY MATERIALS (2017)

Article Chemistry, Multidisciplinary

Self-branched α-MnO2/δ-MnO2 heterojunction nanowires with enhanced pseudocapacitance

Changrong Zhu et al.

MATERIALS HORIZONS (2017)

Article Chemistry, Physical

Mechanism of Zn Insertion into Nanostructured δ-MnO2: A Nonaqueous Rechargeable Zn Metal Battery

Sang-Don Han et al.

CHEMISTRY OF MATERIALS (2017)

Article Nanoscience & Nanotechnology

Enhanced Pseudocapacitive Performance of α-MnO2 by Cation Preinsertion

Nawishta Jabeen et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Article Chemistry, Physical

Parametrisation of a force field of acetamide for simulations of the liquid phase

Jorge A. Aguilar-Pineda et al.

MOLECULAR PHYSICS (2015)

Article Multidisciplinary Sciences

Water-in-salt electrolyte enables high-voltage aqueous lithium-ion chemistries

Liumin Suo et al.

SCIENCE (2015)

Review Chemistry, Multidisciplinary

Aqueous Rechargeable Li and Na Ion Batteries

Haegyeom Kim et al.

CHEMICAL REVIEWS (2014)

Article Chemistry, Multidisciplinary

CHARMM36 all-atom additive protein force field: Validation based on comparison to NMR data

Jing Huang et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

Photochemical Chlorination of Graphene

Bo Li et al.

ACS NANO (2011)

Article Chemistry, Physical

Flexible simple point-charge water model with improved liquid-state properties

YJ Wu et al.

JOURNAL OF CHEMICAL PHYSICS (2006)

Article Spectroscopy

Spectroscopic studies on the cation-anion, cation-solvent and anion-solvent interactions in the LiCF3SO3/acetamide complex system

YS Hu et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2005)