Aminobenzaldehyde convelently modified graphitic carbon nitride photocatalyst through Schiff base reaction: Regulating electronic structure and improving visible-light-driven photocatalytic activity for moxifloxacin degradation

Graphitic carbon nitride (GCN) has been demonstrated to be a potential visible-light-driven photocatalyst for eliminating organic pollutants. However, its practical application is limited by low photocatalytic effi-ciency originating from high recombination of photogenerated charges. In this work, the electronic struc-ture of GCN was regulated by doping aminobenzaldehyde (ABA) into the skeleton through a solid-state Schiff base reaction. Photoelectrochemical characterizations illustrated that the obtained catalyst (CNABA) exhibited narrower band gap, lower recombination rate of photoinduced electron-hole pair and higher charge transfer ability than the pristine GCN, further indicating its excellent photocatalytic activity. Using moxifloxacin (MOX) as a model pollutant, the ABA doping content was firstly optimized and the optimal activity of the CNABA photocatalyst was 3.1 times higher than that of the GCN. Subsequently, the effects of pH value, photocatalyst dosage and MOX concentration on the photocatalytic behavior were also studied. Superior stability and photocatalytic reusability were confirmed by five repeated tests. By substituting tap water/natural lake water for deionized water and sunlight for xenon light, the CNABA also exhibited high elimination efficiency, implying its good practicability. Superoxide radical, hydroxyl radical and photogenerated hole were identified as the main active species to degrade MOX. Finally, possible degradation pathways for MOX to mineralize small molecules were proposed by determining intermediate products during photocatalysis. This work provides a solid-state method to rationally design aromatic system-modified GCN photocatalysts, and the obtained CNABA is a promising visible-light-driven photocatalyst for eliminating antibiotics.(c) 2022 Elsevier Inc. All rights reserved.

Automated summary

Graphitic carbon nitride (GCN) has limited practical application due to low photocatalytic efficiency, but doping aminobenzaldehyde (ABA) into the skeleton can regulate its electronic structure and improve its photocatalytic performance. The optimized CNABA photocatalyst showed 3.1 times higher activity than pristine GCN. CNABA also exhibited excellent stability, photocatalytic reusability, and high elimination efficiency in tap water/natural lake water and sunlight conditions.