Iron and nitrogen anchored hierarchical hollow porous carbon microtubes for an electrocatalytic oxygen evolution reaction

The development of active nonprecious-metal and heteroatom-doped materials is critical for the oxygen evolution reaction (OER). Herein, asphaltene-derived carbon-coated Fe-and N-doped hierarchical hollow porous carbon microtubes were prepared through feasible freeze-drying and carbonization/activation strategies. Cotton with a fibrous morphology acted as a soft template and carbon precursor, while asphaltene with easy graphitization properties was utilized to stabilize the structure of microtubes and accelerate the charge conductivity. Meanwhile, Fe-and N-doping changed the electronic structure of carbon and increased the number of active sites. In particular, the optimum sample displayed excellent OER activity with a lower overpotential of 261.4 mV at 10 mA/cm(2) and Tafel slope of 94.60 mV/dec under alkaline conditions. Moreover, the catalyst demonstrated excellent long-term durability with a 10% attenuation rate after continuous operation for 50 h by the chronoamperometry method at a constant potential of 1.5 V. This work provides a strategy for the effective resource utilization of biomass and asphaltene to prepare highly efficient OER electrocatalysts. (C) 2022 Elsevier B.V. All rights reserved.

Automated summary

In this study, asphaltene-derived carbon-coated Fe and N-doped porous carbon microtubes were successfully prepared using freeze-drying and carbonization/activation strategies. The optimized sample exhibited excellent OER activity and long-term durability under alkaline conditions, demonstrating the potential application of this catalyst. This work provides a new approach for the effective utilization of biomass and asphaltene resources.