4.7 Article

Phase separation and combination of negative and positive magnetocaloric effects in Mn3Ga1-xAxC (A = Sn, Ge, Y)

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 930, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.167376

Keywords

Magnetic properties; Phase transition; Relative cooling power; Entropy; Magnetocaloric effects

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The study focuses on enhancing the magnetocaloric effect (MCE) by combining negative and positive magnetocaloric effects (NMCE and PMCE). By analyzing the magnetic phases and the effects of substituting elements in Mn3GaC, the control of MCE is achieved, expanding the working temperature range. This research is significant for developing magnetocaloric materials with a large MCE and a wide working temperature range.
Mn3GaC exhibits both negative and positive magnetocaloric effects (NMCE and PMCE). Herein, to fabricate high-performance magnetic refrigerants, enhancement of the magnetocaloric effect (MCE) by combining NMCE and PMCE is studied. Compared with composite magnetic refrigerants, an NMCE-PMCE combination in a single magnetic refrigerant considerably enhances the operating temperature range without any loss of magnetic entropy change or relative cooling power (RCP). To realize an NMCE-PMCE combination, the NMCE and PMCE must be clearly identified. The intermediate canted ferromagnetic phase (CFM) between the antiferromagnetic and ferromagnetic phases of Mn3GaC plays a key role in establishing the borderline between the NMCE and PMCE. The effects of substituting Sn, Ge, and Y for Ga on the magnetic phase separation, NMCE, and PMCE of Mn3Ga1-xAxC (A = Sn, Ge, Y) are investigated. Y doping considerably en-hances the CFM state, which establishes a buffer region between the NMCE and PMCE in Mn3Ga0.97Y0.03C. Because of this buffer region, the NMCE and PMCE can be controlled in different temperature ranges for practical applications. We achieve an NMCE-PMCE combination and obtain a super-wide working tem-perature range in Mn3Ga0.97Y0.03C. This work will be helpful in developing a practical magnetocaloric material with a large MCE and a working temperature range.(c) 2022 Elsevier B.V. All rights reserved.

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