Effects of MnO2-doping on growth, structure and electrical properties of lead-free piezoelectric K0.5Na0.5NbO3-BiAlO3 single crystals

K0.5Na0.5NbO3KNN)-based lead-free piezoelectric single crystals have been prepared by the Seed-Free, Solid-State Crystal Growth (SFSSCG) method, and the effects of MnO2 doping on the structural and electrical properties were systematically investigated. The results showed that the MnO2-doping can promote the growth of K0.5Na0.5NbO3-BiAlO3(KNN-BA) single crystals and enhance its electrical properties. Furthermore, the size of the (1 - x)( KNN-BA)-xMnO(2) crystals reached the maximum value of about 18 x 17 x 2 mm(3) at x = 0.005. Also, the color of the crystals did gradually change, from light yellow to dark brown, due to the addition of MnO2. The XRD and refinement results showed that the addition of MnO2, in the range of 0 <= x <= 0.009, did not change the crystalline structure of the perovskite crystals. A two-phase perovskite crystalline structure was present in all crystals: an orthorhombic and a tetragonal phase. The content of the orthorhombic phase decreased, while the content of the tetragonal phase increased, with an increase in the MnO2 content. In addition, the domains in the crystals were mainly composed of 180 & DEG; ones and had a parallel lamellar structure. Also, the smallest average domain width was obtained for crystals with x = 0.003. These crystals had the largest piezoelectric constant of 568 pC/N and an excellent overall performance of d(3)3 = 568 pC/N, Pr = 32.2 mu C/cm(2), Q(m) = 55.3, k(t) = 0.36, kp = 0.39, TC = 418 degrees C, epsilon(r) = 430, and tan delta = 0.015. (c) 2022 Elsevier B.V. All rights reserved.

Automated summary

Lead-free piezoelectric single crystals based on K0.5Na0.5NbO3 (KNN) were prepared using the Seed-Free, Solid-State Crystal Growth (SFSSCG) method, and the effects of MnO2 doping on their structural and electrical properties were investigated. The results showed that MnO2 doping promoted crystal growth and improved electrical properties. The crystal size reached a maximum value of about 18 x 17 x 2 mm³ at a MnO2 content of x = 0.005. The addition of MnO2 resulted in a color change from light yellow to dark brown. XRD analysis revealed that the crystal structure remained unchanged with the addition of MnO2. The crystals exhibited a two-phase perovskite structure with decreasing content of the orthorhombic phase and increasing content of the tetragonal phase. The crystals had a parallel lamellar domain structure composed mainly of 180° ones. The crystal with x = 0.003 exhibited the smallest average domain width and the highest piezoelectric constant of 568 pC/N, as well as excellent overall performance.