Structural, compositional and luminescence studies of Y2O3:Eu3+nanophosphor synthesized by sol-gel method

Europium doped Yttrium oxide (Y2O3) nanophosphors with different doping concentrations were synthe-sized by simple and efficient sol-gel method. The structural, morphological and compositional study was carried out by using XRD, FE-SEM, TEM, EDS, XPS, etc. Results demonstrated that the material is highly crystalline with cubic (body centered) structure and the particles apparently are of spherical shape with particle size around similar to 10-20 nm. EDS results show the presence of Eu-impurity evenly distributed. Optimization of luminescence properties of the material by varying the concentration and annealing temperature show maximum thermoluminescence (TL) sensitivity at 1600 degrees C for 10.0 M% of Eu, however, maximum photoluminescence (PL) intensity was achieved after annealing the nanophosphor at 1200 degrees C. It exhibits a strong red emission with a sharp peak at 612 nm under excitation with UV and visible light ( lambda(ex) = 260, 393, 466 nm). TL studies showed four peaks at 100, 117, 139, and 301 degrees C. However, the first peak fades completely in a day (apparently due to low peak temperature) but the other three peaks are quite stable. The TL response was found to be linear from 120 Gy to 1.0 kGy but becomes sub-linear later in the dose range 1.0-100 kGy. (c) 2022 Elsevier B.V. All rights reserved.

Automated summary

Europium doped Yttrium oxide (Y2O3) nanophosphors were successfully synthesized using a simple and efficient sol-gel method. The material exhibited a highly crystalline cubic structure with spherical particles of size around 10-20 nm. Optimizing the luminescence properties revealed maximum thermoluminescence (TL) sensitivity at 1600 degrees C with 10.0 M% Eu doping, while maximum photoluminescence (PL) intensity was achieved after annealing the nanophosphor at 1200 degrees C. The material showed strong red emission under UV and visible light excitation, with a sharp peak at 612 nm.