Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 944, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.169129
Keywords
In-situ isomorphous recombination; Hybrid supercapacitor; Metal carbonate hydroxide; Acid-etched carbon cloth
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Nickel-cobalt carbonate hydroxides are widely used as battery-type electrode materials, but their electrochemical performance still needs improvement. Most studies have focused on compounding with conductive carbon materials or changing the nanostructure of the material by adjusting the Ni/Co ratio. However, these methods require binder and complicated operation, respectively. In this study, an in-situ isomorphous recombination method was proposed to improve the performance of basic nickel-cobalt carbonate. The synthesized composite electrode exhibited a large specific capacity and good cycling stability.
Nickel-cobalt carbonate hydroxides have been widely employed as battery-type electrode materials. However, in contrast to batteries, improvement in the electrochemical performance of these materials is still needed. Most studies have focused on improving the performance of basic nickel-cobalt carbonate by two means: compounding with conductive carbon materials or changing the nanostructure of the material by adjusting the Ni/Co ratio; however, these methods have the problems of requiring binder and compli-cated operation, respectively. At this point, the in-situ isomorphism method, especially the in-situ iso-morphous recombination method, provides a new way of thinking. Hence, we proposed an in-situ isomorphous recombination method to improve the performance of basic nickel-cobalt carbonate. A facile, two-step hydrothermal strategy was utilized to synthesize isomorphic NiCo(CO3)(OH)2-Co(CO3)0.5(OH) (NCCH-CCH) nanowires on nickel foam. The electrochemical performances of the synthesized electrodes were tested with a three-electrode system. Impressively, the obtained composite electrode exhibited a large specific capacity of 937 C g-1 at 1 A g-1 (1.550 C cm-2 at 1 mA cm-2) and retains 80.9% capacity after 15000 cycles at 20 A g-1. Additionally, employing acid-etched carbon cloth (AECC) as the negative electrode, a NCCH-CCH//AECC hybrid supercapacitor (HSC), which delivers a high energy density of 156.7 mu Wh cm-2 at 0.8 mW cm-2, and exceptional cycling stability (88.9% of capacitance retention after 15000 cycles), is as-sembled. Moreover, the change in pH value at various stages of the reaction was applied to roughly analyse the cause of the disparate morphologies of the two-step hydrothermal products in this study.(c) 2023 Elsevier B.V. All rights reserved.
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