4.7 Article

Highly-doped lanthanide nanomaterials for efficient photothermal conversion - selection of the most promising ions and matrices

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 934, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.167900

Keywords

Photothermal conversion efficiency; Nanoheaters; Lanthanide-doped nanomaterials; Neodymium

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In this study, we systematically compared and quantitatively analyzed the photothermal conversion efficiency of materials doped with rare earth ions. We also investigated the influence of different matrix materials on the efficiency. The research findings suggest that neodymium ions exhibit the highest internal and external photothermal conversion efficiency, and NdVO4 shows promise as a host material for future applications.
Materials doped with rare earth ions are widely used in luminescence applications. However, alternative uses of these materials, such as photothermal conversion, have not yet been systematically investigated. In this work, we systematically and quantitatively compare internal and external photothermal conversion efficiency of materials doped with neodymium, thulium and ytterbium ions, and co-doped with samarium and dysprosium ions. Furthermore, we investigate influence of various matrix materials on photothermal conversion efficiency. These include fluoride, oxide, vanadate and perovskite materials. This was done to determine if photothermal conversion efficiency is dependent on dopant and matrix selection. Our research indicates that the highest internal and external photothermal conversion efficiency is achieved with neo-dymium ions. Moreover, NdVO4 was found to be the most promising host for future applications. Although the internal photothermal conversion efficiency was relatively low (19%), NdVO4 exhibited significant ex-ternal photothermal conversion efficiency of 0.08 L/g center dot cm at 806 nm, which is ca. 14 times higher than that of NaNdF4 at the same wavelength. (c) 2022 Elsevier B.V. All rights reserved.

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