Lignin Microspheres Modified with Magnetite Nanoparticles as a Selenate Highly Porous Adsorbent

Highly porous lignin-based microspheres, modified by magnetite nanoparticles, were used for the first time for the removal of selenate anions, Se(VI), from spiked and real water samples. The influence of experimental conditions: selenate concentration, adsorbent dosage and contact time on the adsorption capacity was investigated in a batch experimental mode. The FTIR, XRD, SEM techniques were used to analyze the structural and morphological properties of the native and exhausted adsorbent. The maximum adsorption capacity was found to be 69.9 mg/g for Se(VI) anions at pH 6.46 from the simulated water samples. The modified natural polymer was efficient in Se(VI) removal from the real (potable) water samples, originated from six cities in the Republic of Serbia, with an overage efficacy of 20%. The regeneration capacity of 61% in one cycle of desorption (0.5 M NaOH as desorption solution) of bio-based adsorbent was gained in this investigation. The examined material demonstrated a significant affinity for Se(VI) oxyanion, but a low potential for multi-cycle material application; consequently, the loaded sorbent could be proposed to be used as a Se fertilizer.

Automated summary

Highly porous lignin-based microspheres modified with magnetite nanoparticles were used for the first time to remove Se(VI) selenate anions from water samples. The research investigated the influence of experimental conditions on the adsorption capacity and analyzed the structural and morphological properties of the adsorbent. The adsorbent showed high affinity for Se(VI) oxyanion but limited potential for multi-cycle material application, making it suitable as a Se fertilizer.