Recycling and utilization of coal gasification residues for fabricating Fe/C composites as novel microwave absorbents

Under the background of a transformation of the global energy structure, coal gasification technology has a wide application prospect, but its by-product, the coal gasification residue (CGR), is still not being efficiently utilized for recycling. The CGR contains abundant carbon components, which could be applied to the microwave absorption field as the carbon matrix. In this study, Fe/CGR composites are fabricated via a two-step method, including the impregnation of Fe3+ and the reduction process. The influence of the different loading capacities of the Fe component on the morphology and electromagnetic properties is studied. Moreover, the loading content of Fe and the surface morphology of the Fe/CGR can be reasonably controlled by adjusting the concentration of the ferric nitrate solution. Meanwhile, Fe particles are evenly inserted on the CGR framework, which expands the Fe/CGR interfaces to enhance interfacial polarization, thus further improving the microwave-absorbing (MA) properties of composites. Particularly, as the Fe3+ concentration is 1.0 mol/L, the Fe/CGR composite exhibits outstanding performance. The reflection loss reaches -39.3 dB at 2.5 mm, and the absorption bandwidth covers 4.1 GHz at 1.5 mm. In this study, facile processability, resource recycling, appropriately matched impedance, and excellent MA performance are achieved. Finally, the Fe/CGR composites not only enhance the recycling of the CGR but also pioneer a new path for the synthesis of excellent absorbents.

Automated summary

Under the global energy structure transformation, coal gasification technology has great potential, but the efficient utilization of coal gasification residue (CGR) as a by-product is still a challenge. In this study, Fe/CGR composites were prepared and their morphologies and electromagnetic properties were studied. The loading content of Fe and the surface morphology were controlled by adjusting the concentration of the ferric nitrate solution. The Fe/CGR composites exhibited outstanding microwave-absorbing properties, making them suitable for novel absorbent synthesis.