4.7 Review

Interfacial engineering in two-dimensional heterojunction photocatalysts

Related references

Note: Only part of the references are listed.
Review Energy & Fuels

A review on S-scheme and dual S-scheme heterojunctions for photocatalytic hydrogen evolution, water detoxification and CO2 reduction

Amit Kumar et al.

Summary: This article provides a review on the transition from Z-scheme to S-scheme photocatalytic materials, discussing different types of heterojunctions and charge transfer mechanisms. It also presents the synthetic routes to S-scheme heterojunctions and highlights their current applications in pollutant degradation, hydrogen production, and CO2 conversion. The commercialization status and existing readiness and bottlenecks of S-scheme heterojunctions are also discussed.
Article Chemistry, Physical

Superb photocatalytic activity of 2D/2D Cl doped g-C3N4 nanodisc/Bi2WO6 nanosheet heterojunction: Exploration of photoinduced carrier migration in S-scheme heterojunction

Wenliang Liu et al.

Summary: The intimately-contact 2D/2D heterojunction structure provides optimal charge transfer/separation interfaces for improved photocatalytic performance. In this study, a Cl doped g-C3N4 nanodisc/regular rectangular Bi2WO6 nanosheet heterojunction (ClCN/Bi2WO6) was constructed using an electrostatic self-assembly technique. The ClCN/Bi2WO6 exhibited significantly enhanced photocatalytic hydrogen generation and photodegradation performance compared to Bi2WO6. The mechanism of charge transfer and separation in the S-scheme heterojunction was investigated using density functional theory calculations. This research advances the development of 2D/2D heterojunction photocatalysts.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Engineering, Environmental

Z-scheme junction Bi2O2(NO3)(OH)/g-C3N4 for promoting CO2 photoreduction

Tongyao Liu et al.

Summary: Constructing a direct Z-scheme heterojunction Bi2O2(NO3)(OH)/g-C3N4 significantly enhances the separation and transfer of photogenerated carriers, resulting in improved photocatalytic CO2 reduction performance.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Boosting interfacial charge separation and photocatalytic activity of 2D/2D g-C3N4/ZnIn2S4S-scheme heterojunction under visible light irradiation

Xu Deng et al.

Summary: The study demonstrated the effectiveness of improving photocatalytic degradation performance by constructing S-scheme heterojunction photocatalysts and successfully synthesized 2D/2D CN/ZIS with different mass ratios. The heterojunction exhibited strong visible light absorption and photo-generated carriers transfer ability, achieving high degradation efficiency of tetracycline under visible light irradiation with stable photocatalytic activity.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Biotechnology & Applied Microbiology

Novel Z-scheme 2D/2D Bi4O5Br2/BiOCl heterojunction with enhanced photocatalytic activity for RhB degradation

Zhiyang Zhang et al.

Summary: A novel Bi4O5Br2/BiOCl (BC2) heterojunction photocatalyst with 2D/2D structure was successfully fabricated via a facile one-pot solvothermal method. The BC2 heterojunction exhibited enhanced photocatalytic activity due to its excellent visible light response, enhanced adsorption capacity, large interface region, internal electric field, and the Z-scheme carrier transfer mechanism. Additionally, slightly acidic condition promoted the degradation of RhB by the BC2 heterojunction.

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY (2022)

Article Chemistry, Physical

Self-assembled ultrathin closely bonded 2D/2D heterojunction for enhanced visible-light-induced photocatalytic oxidation and reaction mechanism insights

Caiyan Gao et al.

Summary: This study presents a novel method to fabricate ultrathin 2D/2D heterojunction nanosheet composites, which exhibit excellent photocatalytic performance for pollutant removal. The heterojunctions possess superior separation and migration efficiency, facilitating the degradation of organic pollutants.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Multidisciplinary

2D/2D Bi2WO6/Protonated g-C3N4 step-scheme heterojunctions for enhancing the photodegradation of 17β-estradiol: promotional role of electrostatic interaction

Yashi Qing et al.

Summary: This study successfully constructed a Bi2WO6/pg-C3N4 2D/2D S-scheme heterojunction for the photodegradation of E2 under visible light. The formation of the heterojunction accelerated the separation of photogenerated carriers and improved the E2 removal efficiency. The research provides new insights for the rational design and synthesis of highly active photocatalysts, with potential applications in the treatment of EDC-containing wastewater.

NEW JOURNAL OF CHEMISTRY (2022)

Review Chemistry, Applied

Role of transition metal oxides in g-C3N4-based heterojunctions for photocatalysis and supercapacitors

Liqi Bai et al.

Summary: g-C3N4 has emerged as a promising 2D photocatalyst due to its unique structure and low cost, but faces limitations. Designing heterojunctions based on g-C3N4 is a promising approach to improving photocatalytic activity and showing potential in electrochemical energy storage.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Chemistry, Physical

Recent advances and challenges in 2D/2D heterojunction photocatalysts for solar fuels applications

I. Ahmad et al.

Summary: This paper discusses the photocatalytic performance of 2D/2D heterojunction systems and strategies to improve their efficiency. It also explores the applications of metal-based and metal-free heterojunction photocatalysts and provides a brief overview of current constraints and predicted results for 2D/2D heterojunction systems.

ADVANCES IN COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Physical

2D/2D BiVO4/CsPbBr3 S-scheme heterojunction for photocatalytic CO2 reduction: Insights into structure regulation and Fermi level modulation

Xiaoyang Yue et al.

Summary: Controlling heterostructure and intrinsic vacancy can optimize the BiVO4/CsPbBr3 S-scheme heterojunction, accelerating dynamic carrier mobility and enhancing CO2-to-CO conversion efficiency.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Multidisciplinary

Realizing Two-Electron Transfer in Ni(OH)2Nanosheets for Energy Storage

Jianxin Kang et al.

Summary: This study reports the discovery of two-electron transfer in monolayer Ni(OH)2 nanosheets, which is different from the traditional one-electron transfer found in multilayer materials. The experimental results show that the monolayer material has an exceptional redox capacity nearly two times higher than the theoretical capacity of one-electron processes. In situ experiments further demonstrate that the monolayer material can transfer two electrons, while the bulk material can only undergo partial transformation.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Energy & Fuels

Transition metal (Ni, co)-doped graphitic carbon nitride/MoS2 heterojunctions as efficient photocatalysts for hydrogen evolution reaction under visible light

Gizem Yanalak et al.

Summary: New photocatalysts consisting of 2D/2D heterojunction of graphitic carbon nitride (gCN) and molybdenum disulfide (MoS2) semiconductors doped with nickel (Ni) or cobalt (Co) were fabricated for the photocatalytic hydrogen evolution reaction (HER) under visible light illumination. The prepared gCN/MoS2-Ni and gCN/MoS2-Co photocatalysts exhibited enhanced HER activities and stabilities compared to pristine gCN and binary gCN/MoS2 heterojunctions.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2022)

Article Chemistry, Physical

Two-dimensional/two-dimensional heterojunction-induced accelerated charge transfer for photocatalytic hydrogen evolution over Bi5O7Br/Ti3C2: Electronic directional transport

Fangxia Xie et al.

Summary: Regulating electron density at the active site by electronic directional transport from special channels is an effective strategy to accelerate the reaction rate in photocatalytic water splitting. In this study, a novel 2D/2D Bi5O7Br/Ti3C2 heterojunction was fabricated, which exhibited improved photocatalytic hydrogen evolution performance under visible light irradiation.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Engineering, Environmental

Ultrathin layered 2D/2D heterojunction of ReS2/high-crystalline g-C3N4 for significantly improved photocatalytic hydrogen evolution

Tingyu Yang et al.

Summary: In this study, an ultrathin layered 2D/2D heterojunction catalyst ReS2/CCN was successfully constructed, which exhibited excellent photocatalytic performance with a high H-2 evolution rate under visible light irradiation. The efficient charge transport of highly crystalline CCN, the strong visible light harvesting of ReS2 nanoflakes, and the synergistic effect of the ultrathin layered 2D/2D heterojunction are the main reasons for its enhanced performance.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Efficient interfacial charge transfer of 2D/2D CoP/CdS heterojunction for extremely boosted photocatalytic H2 evolution performance

Manjun Fu et al.

Summary: Constructing 2D/2D heterojunction photocatalysts can significantly improve the photocatalytic H2 evolution performance. In this study, 2D/2D CoP/CdS heterojunctions were successfully fabricated and extensively characterized. The experimental results showed that the 2D/2D CoP/CdS heterojunction exhibited significantly enhanced photocatalytic H2 evolution rate.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Engineering, Chemical

Decorating 2D Ti3C2 on flower-like hierarchical Bi2WO6 for the 2D/2D heterojunction construction towards photodegradation of tetracycline antibiotics

Zhonghui Han et al.

Summary: This study constructed a 2D/2D heterojunction in traditional metal oxide photocatalyst and significantly improved the efficiency of photocatalytic degradation by decorating 2D Ti3C2 on nanosheet units. The research is expected to promote the environmental application of solar-driven antibiotics degradation technology.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Chemistry, Physical

Construction of rGO-coupled C3N4/C3N5 2D/2D Z-scheme heterojunction to accelerate charge separation for efficient visible light H2 evolution

Dong Liu et al.

Summary: A novel N-rich carbon nitride material C3N5 was designed and prepared in this study, which formed a sandwich heterojunction with C3N4, demonstrating a synergistic effect of electron-rich and hole-rich reservoirs. The 2D/2D heterojunction was applied to achieve efficient visible-light-responsive activity for H2 evolution reaction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Engineering, Environmental

Enhanced electrocatalytic full water-splitting reaction by interfacial electric field in 2D/2D heterojunction

Hyeonuk Choi et al.

Summary: A carbon-based electrocatalyst, g-C3N4/rGO, was synthesized via a simple electrostatic self-assembly method and used for full water-splitting. Compared to other 2D structured materials, g-C3N4/rGO exhibited lower overpotential and Tafel slope, indicating higher efficiency.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Applied

Selective CO2 photoreduction to CH4 mediated by dimension-matched 2D/2D Bi3NbO7/g-C3N4 S-scheme heterojunction

Kai Wang et al.

Summary: This study presents an ultrathin dimension-matched S-scheme Bi3NbO7/g-C3N4 heterostructure catalyst that enables highly selective photocatalytic reduction of CO2 to CH4. The presence of an internal electric field between Bi3NbO7 and g-C3N4 facilitates the transfer of photogenerated electrons, resulting in efficient and selective CO2 photoreduction.

CHINESE JOURNAL OF CATALYSIS (2022)

Article Multidisciplinary Sciences

Synergetic enhancement of surface reactions and charge separation over holey C3N4/TiO2 2D heterojunctions

Yuting Xiao et al.

Summary: Efficient charge separation and rapid interfacial reaction kinetics play crucial roles in determining the efficiency of photocatalytic hydrogen evolution. In this study, a 2D heterojunction photocatalyst named HCN/TiO2 was designed, which demonstrated superior photocatalytic performance due to optimized structure and intimate interfacial contact, providing a promising strategy for developing high-performance clean energy applications.

SCIENCE BULLETIN (2021)

Article Chemistry, Physical

The In-situ Growth NiFe-layered Double Hydroxides/g-C3N4 Nanocomposite 2D/2D Heterojunction for Enhanced Photocatalytic CO2 Reduction Performance

Xiaoya Zhao et al.

Summary: The tightly 2D/2D heterojunction of g-C3N4/NiFe-layered double hydroxides (NiFe-LDH) prepared in situ showed improved transfer pathway of photogenerated electrons and holes, resulting in reduced recombination rate and increased efficiency and selectivity for CO2 reduction. The addition of g-C3N4 also modified the surface morphology and ductility of NiFe-LDH, providing more reaction sites for the reduction of CO2.

CATALYSIS LETTERS (2021)

Article Environmental Sciences

In-situ development of metal organic frameworks assisted ZnMgAl layered triple hydroxide 2D/2D hybrid as an efficient photocatalyst for organic dye degradation

K. Bhuvaneswari et al.

Summary: A Metal organic framework (MOF) supported layered triple hydroxide (LTH) 2D/2D hybrid material was prepared using a simple hydrothermal method, and its photophysical properties were analyzed through various methods. The degradation efficiency of the MOF-5/LTH hybrid sample was found to be significantly higher, attributed to enhanced visible light absorption and efficient separation and transportation of photoinduced electrons and holes.

CHEMOSPHERE (2021)

Article Chemistry, Physical

Novel S-scheme WO3/CeO2 heterojunction with enhanced photocatalytic degradation of sulfamerazine under visible light irradiation

Ashkan Bahadoran et al.

Summary: In this study, hierarchical WO3-CeO2 hollow sphere heterojunctions were prepared via a two-step hydrothermal method and showed enhanced photocatalytic activity, with the highest degradation of sulfamerazine achieved on the WO3-CeO2 heterojunction with 30% CeO2 content. The efficient separation of charge carriers and an S-scheme charge transfer mechanism were the key factors contributing to the improved performance.

APPLIED SURFACE SCIENCE (2021)

Article Chemistry, Physical

KCa2Nb3O10/ZnIn2S4 nanosheet heterojunctions with improved charge separation efficiency for efficient photocatalytic CO2 reduction

Deli Jiang et al.

Summary: Construction of face-to-face heterojunctions is an effective strategy for efficient photocatalytic CO2 reduction. The ZnIn2S4/KCNO 2D/2D nanosheet heterojunctions exhibit significantly enhanced photocatalytic activity, with the CO production rate much higher than bare ZnIn2S4 and Ka(2)Nb(3)O(10). These heterojunctions demonstrate improved charge transfer and separation efficiency.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Ultrathin Z-scheme 2D/2D N-doped HTiNbO5 nanosheets/g-C3N4 porous composites for efficient photocatalytic degradation and H2 generation under visible light

Chao Liu et al.

Summary: The construction of ultrathin Z-scheme two-dimensional (2D)/2D N-doped HTiNbO5 nanosheets/gC(3)N(4) heterojunction composites through a two-step exfoliation-restacking process has shown enhanced photocatalytic performance for organic dye degradation and hydrogen generation under visible light irradiation. This is achieved by effectively spatial separation of charge carriers in a 2D/2D heterojunction structure, leading to improved catalytic activities.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Physical

Protonated g-C3N4 cooperated with Co-MOF doped with Sm to construct 2D/2D heterojunction for integrated dye-sensitized photocatalytic H2 evolution

Sheng Zhao et al.

Summary: A dye-sensitive photocatalytic H-2 evolution system with a unique structure was developed, which effectively enhances the efficiency of photocatalytic H-2 production. By protonation and heterojunction design, recombination of photogenerated excitons was effectively suppressed, leading to highly efficient photocatalytic hydrogen evolution.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Review Chemistry, Multidisciplinary

Vacancy Engineering of Ultrathin 2D Materials for Photocatalytic CO2 Reduction

Yingxin Ma et al.

Summary: This review focuses on vacancy-engineered ultrathin materials for CO2 photoreduction, discussing different types of vacancies and their roles in the catalytic process, and presenting various vacancy engineering strategies. Future developments and associated challenges concerning defective ultrathin 2D materials are also discussed.

CHEMNANOMAT (2021)

Article Nanoscience & Nanotechnology

Ambient-Stable Black Phosphorus-Based 2D/2D S-Scheme Heterojunction for Efficient Photocatalytic CO2 Reduction to Syngas

Cao Chen et al.

Summary: An ambient-stable and effective 2D/2D heterostructure of BP/bismuth tungstate (Bi2WO6) with oxygen vacancy is designed for syngas production via photocatalytic CO2 reduction, resolving the stability problem of BP nanosheets and greatly improving charge transfer efficiency. This work achieves high generation rates of CO and H2, along with desirable CO/H2 ratios for industrial applications, making it an efficient and ambient-stable BP-based photocatalyst for syngas production by CO2 reduction at mild conditions.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Physical

Van der Waals heterojunction for selective visible-light-driven photocatalytic CO2 reduction

Jun Li et al.

Summary: In this study, atomically thin carbon nitride (CN) coupled with Bi9O2.5S6 (BOS) nanoplates to form a 2D/2D Van der Waals heterojunction for CO2 photocatalytic reduction, achieving a high CO generation rate. The 2D/2D VDW heterojunction can adsorb CO* more strongly on BOS than CN, leading to hydrogenation before desorption and explaining the product selectivity.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Coupling ferroelectric polarization and anisotropic charge migration for enhanced CO2 photoreduction

Hongjian Yu et al.

Summary: The study on CO2 photoreduction into solar fuels is significant. SrBi2Nb2O9 nanosheets demonstrate outstanding CO2 reduction performance, with ferroelectric polarization and anisotropic charge migration playing critical roles.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Hierarchical Sheet-on-Sheet ZnTi-LDHs/g-C3N4 composites with enhanced photocatalytic activity prepared by mechanical mixing

Luyao Zhang et al.

Summary: The study investigates the structure, morphology, interfacial contact, and photocatalytic properties of ZnTi-LDHs/g-C3N4 composites prepared by different methods. The experimental results show that the ZnTi-LDHs/g-C3N4 composites prepared by the mechanical mixing method exhibit better photocatalytic activity due to the hierarchical sheet-on-sheet contact between g-C3N4 and ZnTi-LDHs, which efficiently promotes photo-induced charge separation. This study demonstrates a feasible way for further design and synthesis of photocatalysts with a 2D/2D heterojunction with sheet-on-sheet contact.

APPLIED CLAY SCIENCE (2021)

Review Chemistry, Multidisciplinary

Recent advances in BiOBr-based photocatalysts for environmental remediation

Lingyou Meng et al.

Summary: This review summarizes the latest developments of BiOBr-based photocatalysts for environmental remediation, with a focus on strategies for controlling product morphology and improving photocatalytic activity, as well as their applications in environmental purification and CO2 reduction.

CHINESE CHEMICAL LETTERS (2021)

Article Materials Science, Multidisciplinary

2D/2D NiCo-MOFs/GO hybrid nanosheets for high-performance asymmetrical supercapacitor

Sha Li et al.

Summary: Two-dimensional NiCo-MOF/GO hybrid nanosheets were prepared by ultrasonic method, constructing a conductive network to enhance electron conductivity and prevent aggregation, leading to high specific capacity. The asymmetric supercapacitor (ASC) constructed by NCMG and activated carbon exhibited a high energy density at a power density level.

DIAMOND AND RELATED MATERIALS (2021)

Article Materials Science, Multidisciplinary

Photocatalytic degradation of mixed pollutants in aqueous wastewater using mesoporous 2D/2D TiO2(B)-BiOBr heterojunction

Liping Han et al.

Summary: The mesoporous 2D/2D TiO2(B)-BiOBr heterojunction photocatalyst shows outstanding photocatalytic activity for mixed pollutants in wastewater. The coupling structure enhances disconnection of photoexcited carriers and increases absorption and reaction sites.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Physical

Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation

Jianxin Kang et al.

Summary: Monolayer materials offer an extra degree of freedom to modulate electronic structures and catalytic performances, promoting dynamic active site generation for the oxygen evolution reaction at lower potentials. Lattice doping with cobalt tunes the electronic structure and reduces overpotential, while in situ experiments reveal valence state oscillation in NiCo hydroxides as a fundamental mechanism for active site generation.

NATURE CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Synergistic Polarization Engineering on Bulk and Surface for Boosting CO2 Photoreduction

Lizhen Liu et al.

Summary: The study combined corona poling and surface I-grafting to enhance charge separation and CO2 affinity of Bi4Ti3O12, resulting in a significant increase in CO production rate. The synergistic effect of ferroelectric polarization and surface ion grafting promotes CO2 photoreduction efficiently.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Physical

Facet-selective charge separation in two-dimensional bismuth-based photocatalysts

Cheng Hu et al.

Summary: This review summarizes recent advances in facet design of two-dimensional bismuth-based semiconductors, focusing on facet-dependent charge carrier migration and photocatalytic applications, with highlighted strategies such as pH regulation and piezoelectric/ferroelectric polarization for controlling facet-selective charge separation.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Review Materials Science, Multidisciplinary

Van der Waals Heterostructures by Design: From 1D and 2D to 3D

Peiqi Wang et al.

Summary: Heterostructures are formed by combining two types of materials with different properties, providing the material foundation for modern electronic and optoelectronic devices. The use of van der Waals force allows for a bond-free strategy in creating heterostructures with designable electronic interfaces.

MATTER (2021)

Article Energy & Fuels

Bi/BiOCl Nanosheets Enriched with Oxygen Vacancies to Enhance Photocatalytic CO2 Reduction

Shuqi Wu et al.

Summary: In this study, BiOCl nanosheets were enriched with oxygen vacancies by in situ reduction and deposition of Bi on the surface, leading to significantly enhanced photocatalytic activity for CO2 reduction.

TRANSACTIONS OF TIANJIN UNIVERSITY (2021)

Review Chemistry, Multidisciplinary

Bismuth-based Z-scheme photocatalytic systems for solar energy conversion

Lina Guo et al.

Summary: Photocatalysis using inexhaustible sunlight can effectively address environmental pollution and energy supply issues. Designing high-efficiency photocatalysts with strong light absorption and charge separation is crucial. Bismuth-based materials have unique characteristics, but the limitations of light absorption and charge separation hinder their applications. Constructing Z-scheme photocatalysts inspired by natural photosynthesis provides a feasible strategy to overcome these challenges.

MATERIALS CHEMISTRY FRONTIERS (2021)

Article Chemistry, Physical

Bifunctional black phosphorus: coupling with hematite for Z-scheme photocatalytic overall water splitting

Ming Wang et al.

Summary: The study presents a novel all solid-state 2D-2D Z-scheme photocatalytic system utilizing black phosphorus and α-Fe2O3 materials to enhance overall water splitting efficiency, without the need for sacrificial agents. It highlights the importance of solid charge transfer mediators in accelerating interface charge migration and separation.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Applied

2D/2D step-scheme α-Fe2O3/Bi2WO6 photocatalyst with efficient charge transfer for enhanced photo-Fenton catalytic activity

Wenliang Wang et al.

Summary: In this study, a 2D/2D step-scheme alpha-Fe2O3/Bi2WO6 (FO/BWO) heterostructure photo-Fenton catalyst was successfully synthesized using a facile hydrothermal method, exhibiting significantly enhanced catalytic activity attributed to the combination of H2O2 and FO under light illumination and the presence of the 2D/2D S-scheme heterostructure. The improved catalytic performance was mainly due to the large contact surface, abundant active sites, and efficient separation rate of photogenerated carriers.

CHINESE JOURNAL OF CATALYSIS (2021)

Review Chemistry, Physical

Inside-and-Out Semiconductor Engineering for CO2 Photoreduction: From Recent Advances to New Trends

Shuobo Wang et al.

Summary: This article provides a timely and comprehensive review focusing on recent advances in the design strategies for photocatalytic CO2 conversion. It emphasizes the importance of key parameters in tailoring the size, morphology, bandgap, and other properties of photocatalysts to improve CO2 conversion efficiency and selectivity. New trends and strategies in structural design to meet the demands for prominent CO2 photoreduction activity are also introduced, offering a comprehensive guideline for designing state-of-the-art photocatalysts with well-defined structures for CO2 conversion.

SMALL STRUCTURES (2021)

Review Chemistry, Physical

The nonmetal modulation of composition and morphology of g-C3N4-based photocatalysts

Fang He et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

Article Materials Science, Multidisciplinary

Liquid exfoliating CdS and MoS2 to construct 2D/2D MoS2/CdS heterojunctions with significantly boosted photocatalytic H2 evolution activity

Minghui Xiong et al.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2020)

Article Chemistry, Multidisciplinary

Metal-Free 2D/2D Black Phosphorus and Covalent Triazine Framework Heterostructure for CO2 Photoreduction

Jian Li et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Materials Science, Multidisciplinary

Fe3O4 nanoparticles functionalized GO/g-C3N4 nanocomposite: An efficient magnetic nanoadsorbent for adsorptive removal of organic pollutants

Shraban Ku Sahoo et al.

MATERIALS CHEMISTRY AND PHYSICS (2020)

Review Engineering, Environmental

Powerful combination of 2D g-C3N4 and 2D nanomaterials for photocatalysis: Recent advances

Xin Zhang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Chemistry, Physical

Construction of novel BiOIO3/MoS2 2D/2D heterostructures with enhanced photocatalytic activity

Mingli Lu et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

Review Chemistry, Multidisciplinary

S-Scheme Heterojunction Photocatalyst

Quanlong Xu et al.

Review Green & Sustainable Science & Technology

Heterojunction Photocatalysts Based on 2D Materials: The Role of Configuration

Qian Su et al.

ADVANCED SUSTAINABLE SYSTEMS (2020)

Article Chemistry, Multidisciplinary

Z-Scheme 2D/2D Heterojunction of CsPbBr3/Bi2WO6for Improved Photocatalytic CO2Reduction

Yong Jiang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Engineering, Environmental

Metal-free Z-scheme 2D/2D VdW heterojunction for high-efficiency and durable photocatalytic H2 production

Hongjun Dong et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Electrochemistry

Co(OH)2/MXene composites for tunable pseudo-capacitance energy storage

Hanmei Jiang et al.

ELECTROCHIMICA ACTA (2020)

Article Multidisciplinary Sciences

Unique S-scheme heterojunctions in self-assembled TiO2/CsPbBr3 hybrids for CO2 photoreduction

Feiyan Xu et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Copper-linked 1T MoS2/Cu2O Heterostructure for Efficient Photocatalytic Hydrogen Evolution

Yin Yage et al.

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES (2020)

Article Chemistry, Applied

Highly efficient visible-light photocatalytic H-2 evolution over 2D-2D CdS/Cu7S4 layered heterojunctions

Doudou Ren et al.

CHINESE JOURNAL OF CATALYSIS (2020)

Article Chemistry, Multidisciplinary

Boosting Visible-Light Photocatalytic Hydrogen Evolution with an Efficient CuInS2/ZnIn2S4 2D/2D Heterojunction

Zhongjie Guan et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Review Chemistry, Multidisciplinary

2D/2D Heterojunctions for Catalysis

Juan Su et al.

ADVANCED SCIENCE (2019)

Article Chemistry, Physical

Ultrathin 2D/2D WO3/g-C3N4 step-scheme H2-production photocatalyst

Junwei Fu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

Review Chemistry, Physical

Ultrathin structured photocatalysts: A versatile platform for CO2 reduction

Jun Xiong et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

Article Materials Science, Multidisciplinary

2D BiVO4/g-C3N4 Z-scheme photocatalyst for enhanced overall water splitting

Hanyi Xie et al.

JOURNAL OF MATERIALS SCIENCE (2019)

Article Chemistry, Physical

Novel g-C3N4/g-C3N4 S-scheme isotype heterojunction for improved photocatalytic hydrogen generation

Quanlong Xu et al.

APPLIED SURFACE SCIENCE (2019)

Article Chemistry, Physical

2D-2D heterostructured CdS-CoP photocatalysts for efficient H2 evolution under visible light irradiation

Qixiao Gai et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2019)

Review Chemistry, Multidisciplinary

Kinetics of Graphene and 2D Materials Growth

Jichen Dong et al.

ADVANCED MATERIALS (2019)

Article Chemistry, Multidisciplinary

Z-Scheme 2D/2D Heterojunction of Black Phosphorus/Monolayer Bi2WO6 Nanosheets with Enhanced Photocatalytic Activities

Jundie Hu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Physical

2D MOFs enriched g-C3N4 nanosheets for highly efficient charge separation and photocatalytic hydrogen evolution from water

Yinghua Liang et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2019)

Review Chemistry, Physical

A critical review in strategies to improve photocatalytic water splitting towards hydrogen production

Nur Fajrina et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2019)

Article Materials Science, Multidisciplinary

Two-dimensional photocatalyst design: A critical review of recent experimental and computational advances

Yunxuan Zhao et al.

Materials Today (2019)

Article Chemistry, Multidisciplinary

Construction of a Two-Dimensional Composite Derived from TiO2 and SnS2 for Enhanced Photocatalytic Reduction of CO2 into CH4

Houde She et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

2D-2D Heterostructured UNiMOF/g-C3N4 for Enhanced Photocatalytic H2 Production under Visible-Light Irradiation

Aihui Cao et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Green & Sustainable Science & Technology

2D/2D Graphitic Carbon Nitride/Antimonene Heterostructure: Structural Characterization and Application in Photocatalysis

Jesus Barrio et al.

ADVANCED SUSTAINABLE SYSTEMS (2019)

Article Chemistry, Multidisciplinary

Superlattices based on van der Waals 2D materials

Yu Kyoung Ryu et al.

CHEMICAL COMMUNICATIONS (2019)

Article Nanoscience & Nanotechnology

g-C3N4/NiAl-LDH 2D/2D Hybrid Heterojunction for High-Performance Photocatalytic Reduction of CO2 into Renewable Fuels

Surendar Tonda et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

2D/2D Heterojunction of Ultrathin MXene/Bi2WO6 Nanosheets for Improved Photocatalytic CO2 Reduction

Shaowen Cao et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

Article Chemistry, Physical

Covalently bonded 2D/2D O-g-C3N4/TiO2 heterojunction for enhanced visible-light photocatalytic hydrogen evolution

Ruyi Zhong et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

Review Chemistry, Multidisciplinary

Interface-Assisted Synthesis of 2D Materials: Trend and Challenges

Renhao Dong et al.

CHEMICAL REVIEWS (2018)

Article Chemistry, Physical

C2N/WS2 van der Waals type-II heterostructure as a promising water splitting photocatalyst

Ritesh Kumar et al.

JOURNAL OF CATALYSIS (2018)

Article Engineering, Chemical

A three-dimensional (3D) structured Bi2WO6-palygorskite composite and their enhanced visible light photocatalytic property

Yanqing Yang et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2018)

Review Chemistry, Physical

Role of Interfaces in Two-Dimensional Photocatalyst for Water Splitting

Tongming Su et al.

ACS CATALYSIS (2018)

Review Chemistry, Multidisciplinary

Recent Advances in Growth of Novel 2D Materials: Beyond Graphene and Transition Metal Dichalcogenides

Dechao Geng et al.

ADVANCED MATERIALS (2018)

Review Chemistry, Multidisciplinary

Interface Characterization and Control of 2D Materials and Heterostructures

Xiaolong Liu et al.

ADVANCED MATERIALS (2018)

Article Physics, Applied

Direct Z-scheme photocatalytic overall water splitting on 2D CdS/InSe heterostructures

Yingcai Fan et al.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2018)

Review Chemistry, Multidisciplinary

Two-dimensional polymeric carbon nitride: structural engineering for optimizing photocatalysis

Wenjun Jiang et al.

SCIENCE CHINA-CHEMISTRY (2018)

Article Engineering, Chemical

A Specifically Exposed Cobalt Oxide/Carbon Nitride 2D Heterostructure for Carbon Dioxide Photoreduction

Xingwang Zhu et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2018)

Article Chemistry, Physical

Selective CO2 Reduction on 2D Mesoporous Bi Nanosheets

Hui Yang et al.

ADVANCED ENERGY MATERIALS (2018)

Article Chemistry, Multidisciplinary

Z-Scheme g-C3N4/Bi4NbO8Cl Heterojunction for Enhanced Photocatalytic Hydrogen Production

Yong You et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

Article Chemistry, Multidisciplinary

A Molecular Pillar Approach To Grow Vertical Covalent Organic Framework Nanosheets on Graphene: Hybrid Materials for Energy Storage

Jinhua Sun et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Fast Photoelectron Transfer in (Cring)-C3N4 Plane Heterostructural Nanosheets for Overall Water Splitting

Wei Che et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Metal-Free Photocatalyst for H2 Evolution in Visible to Near-Infrared Region: Black Phosphorus/Graphitic Carbon Nitride

Mingshan Zhu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Review Materials Science, Multidisciplinary

Two-dimensional van der Waals heterojunctions for functional materials and devices

Wei Hu et al.

JOURNAL OF MATERIALS CHEMISTRY C (2017)

Review Engineering, Mechanical

A review on mechanics and mechanical properties of 2D materials-Graphene and beyond

Deji Akinwande et al.

EXTREME MECHANICS LETTERS (2017)

Article Chemistry, Multidisciplinary

Precise Formation of a Hollow Carbon Nitride Structure with a Janus Surface To Promote Water Splitting by Photoredox Catalysis

Dandan Zheng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Review Biophysics

2D and 3D graphene materials: Preparation and bioelectrochemical applications

Hongcai Gao et al.

BIOSENSORS & BIOELECTRONICS (2015)

Review Chemistry, Multidisciplinary

Waltzing with the Versatile Platform of Graphene to Synthesize Composite Photocatalysts

Nan Zhang et al.

CHEMICAL REVIEWS (2015)

Article Chemistry, Physical

Relationship between surface hydroxyl groups and liquid-phase photocatalytic activity of titanium dioxide

Wenjuan Li et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2015)

Article Chemistry, Multidisciplinary

Two-Step Growth of Two-Dimensional WSe2/MoSe2 Heterostructures

Yongji Gong et al.

NANO LETTERS (2015)

Review Green & Sustainable Science & Technology

Environmental issues associated with wind energy - A review

Kaoshan Dai et al.

RENEWABLE ENERGY (2015)

Article Chemistry, Analytical

Hydrogen gas sensing properties of MoS2/Si heterojunction

Yunjie Liu et al.

SENSORS AND ACTUATORS B-CHEMICAL (2015)

Article Chemistry, Multidisciplinary

Two-dimensional layered composite photocatalysts

Jingxiang Low et al.

CHEMICAL COMMUNICATIONS (2014)

Article Chemistry, Physical

Vertical and in-plane heterostructures from WS2/MoS2 monolayers

Yongji Gong et al.

NATURE MATERIALS (2014)

Article Chemistry, Physical

Phase-engineered low-resistance contacts for ultrathin MoS2 transistors

Rajesh Kappera et al.

NATURE MATERIALS (2014)

Article Nanoscience & Nanotechnology

Lateral epitaxial growth of two-dimensional layered semiconductor heterojunctions

Xidong Duan et al.

NATURE NANOTECHNOLOGY (2014)

Review Chemistry, Multidisciplinary

Roles of Cocatalysts in Photocatalysis and Photoelectrocatalysis

Jinhui Yang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2013)

Article Nanoscience & Nanotechnology

Two-Dimensional Interface Engineering of a Titania-Graphene Nanosheet Composite for Improved Photocatalytic Activity

Jing Sun et al.

ACS APPLIED MATERIALS & INTERFACES (2013)

Article Chemistry, Physical

Towards efficient solar hydrogen production by intercalated carbon nitride photocatalyst

Honglin Gao et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2013)

Article Chemistry, Multidisciplinary

Facet-Mediated Photodegradation of Organic Dye over Hematite Architectures by Visible Light

Xuemei Zhou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Review Chemistry, Multidisciplinary

Graphene-based semiconductor photocatalysts

Quanjun Xiang et al.

CHEMICAL SOCIETY REVIEWS (2012)

Article Chemistry, Multidisciplinary

Size and Structure Matter: Enhanced CO2 Photoreduction Efficiency by Size-Resolved Ultrafine Pt Nanoparticles on TiO2 Single Crystals

Wei-Ning Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

Photocatalytic Reduction of Carbon Dioxide over Ag Cocatalyst-Loaded ALa4Ti4O15 (A = Ca, Sr, and Ba) Using Water as a Reducing Reagent

Kosuke Iizuka et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Chemistry, Multidisciplinary

Photoluminescence from Chemically Exfoliated MoS2

Goki Eda et al.

NANO LETTERS (2011)

Review Chemistry, Multidisciplinary

Toward Solar Fuels: Photocatalytic Conversion of Carbon Dioxide to Hydrocarbons

Somnath C. Roy et al.

ACS NANO (2010)

Article Polymer Science

Physical interactions at carbon nanotube-polymer interface

M Wong et al.

POLYMER (2003)