Promoting adsorption performance and mechanical strength in composite porous gel film

Starch is widely used to prepare biodegradable films due to its superior biocompatibility, low immunogenicity, and renewability. In this work, a novel K+/carrageenan porous-starch/casein gel film with high oil absorption was prepared using modified porous starch. Optimal gel stability and uniformity were obtained when adding 10 mg/mL k-carrageenan and 2 mg/mL K+ to 2 mg/mL microgels, with significantly reduced crystallinity and elasticity and increased tensile strength. The concentration of k-carrageenan was the main factor affecting gel strength and the hydrophilic and mechanical properties of the film. In addition, the film-forming solution showed excellent fluidity and spreading typical of non-Newtonian fluids. The film also exhibited a highly porous structure, as visualized by SEM and AFM, in line with a cumulative oil absorption rate of 87.5 % within 20 min, which was significantly higher than that obtained with glutinous rice starch. In conclusion, reinforcement of starch-based microgels as described in this study can maximize the film's adsorption performance and mechanical properties, with promising applications in skin care and beauty products.

Automated summary

In this study, a high oil-absorbing K+/carrageenan porous-starch/casein gel film was prepared using modified porous starch. The film exhibited optimal gel stability and uniformity, reduced crystallinity and elasticity, increased tensile strength. The concentration of carrageenan was found to be the main factor affecting the gel strength and film properties. The film-forming solution showed non-Newtonian fluid behavior and the film had a highly porous structure and excellent oil absorption performance.