4.7 Article

Biomass-based hydrogels with high ductility, self-adhesion and conductivity inspired by starch paste for strain sensing

Journal

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
Volume 222, Issue -, Pages 1211-1220

Publisher

ELSEVIER
DOI: 10.1016/j.ijbiomac.2022.09.181

Keywords

Modified starch; Biomass-based hydrogel; Stretchability adhesion strength; Strain sensor

Funding

  1. National Natural Science Foundation of China
  2. Research on Sci- ence and Technology of Education Department of Liaoning Province Project
  3. [22278045]
  4. [22278048]
  5. [31771914]
  6. [31800498]
  7. [J2020056]
  8. [2022 -MS -344]

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Currently, hydrogel sensors used for health monitoring often require external fixation methods, which can cause allergic reactions and reduce monitoring accuracy. However, a biomass-based hydrogel sensor has been developed to address this issue and exhibits excellent properties such as good stretchability, high adhesion strength, and conductivity, making it highly promising for various applications in wearable devices.
Currently, hydrogel sensors for health monitoring require external tapes, bandages or adhesives to immobilize them on the surface of human skin. However, these external fixation methods easily lead to skin allergic reactions and the decline of monitoring accuracy. A simple strategy to solve this problem is to endow hydrogel sensors with good adhesion. Inspired by the starch paste adhesion mechanism, a biomass-based hydrogel with good conductivity and high repetitive adhesion strength was prepared by introducing modified starch into polyacrylic acid hydrogel system. The properties of biomass-based hydrogels could be controlled by changing the proportion of amylose and amylopectin. The biomass-based hydrogel exhibited a variety of excellent properties, including good stretchability (1290 %), high adhesion strength (pig skin: 46.51 kPa) and conductivity (2.3 S/m). Noticeably, the repeated adhesive strength of biomass-based hydrogel did not decrease with the increase of adhesion times. The strain sensor based on the biomass-based hydrogel could accurately monitor the large-scale and small movements of the human body, and had broad application prospects in the field of flexible wearable devices.

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