4.7 Article

Synthesis of ZnCo2O4-ZnO nanoparticles for the effective elimination of asphaltene from crude oil

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 148, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.inoche.2022.110222

Keywords

Nanocatalyst Green chemistry; ZnCo2O4 Crude oil; Asphaltene

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An advanced method for fabricating highly effective ZnCo2O4-ZnO nanocatalyst using Polyethylene glycol (PEG) as a fuel and stabilizer was successfully developed. The dimensions, performance, and shape of ZnCo2O4-ZnO nanoparticles were effectively controlled by changing the type and quantity of PEG. Characterization of the produced ZnCo2O4-ZnO nanostructures was conducted using FTIR, XRD, TGA, SEM, and TEM. The ZnCo2O4-ZnO nanostructures showed excellent adsorption and elimination properties for asphaltene in crude oil, and the catalyst could be reused multiple times without significant loss in activity and selectivity.
An advanced and eco-friendly method for the fabrication of ZnCo2O4-ZnO nanostructures (NSs), as highly effective nanocatalyst, was expanded using Polyethylene glycol (PEG) which is a new type of fuel and stabilizer. The influence of effectual elements such as the type of PEG and its quantity on the morphological features and function of ZnCo2O4-ZnO nanocatalyst was probed. The findings showed that changing the type of PEG and its amount can effectively control the dimensions, performance, and shape of ZnCo2O4-ZnO nanoparticles. The properties of produced ZnCo2O4-ZnO NSs were probed by FTIR, XRD, TGA, and, SEM, TEM. ZnCo2O4-ZnO NSs were employed as an extremely effectual recoverable adsorbent for the adsorption and elimination of asphaltene from crude oil. The existence of heterogeneity did not stop the progress. The products were effortlessly isolated from the green media, and the catalyst was employed many times without a distinguished drop in activity and selectivity.

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