Journal
INORGANIC CHEMISTRY
Volume 62, Issue 1, Pages 25-29Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c03640
Keywords
-
Categories
Ask authors/readers for more resources
In this study, Fe3O4 nanoparticles decorated TiO2 nanoribbon array on titanium plate (Fe3O4@TiO2/TP) was developed as an efficient electrocatalyst for NO3- reduction to produce NH3. Fe3O4@TiO2/TP achieved a high NH3 yield and Faradaic efficiency in 0.1 M phosphate-buffered saline and 0.1 M NO3- electrolyte, and demonstrated excellent stability during long-time electrolysis.
Electrochemical nitrate (NO3-) reduction is a potential approach to produce high-value ammonia (NH3) while removing NO3- pollution, but it requires electrocatalysts with high efficiency and selectivity. Herein, we report the development of Fe3O4 nanoparticles decorated TiO2 nanoribbon array on titanium plate (Fe3O4@TiO2/TP) as an efficient electrocatalyst for NO3- -to-NH3 conversion. When operated in 0.1 M phosphate-buffered saline and 0.1 M NO3-, such Fe3O4@TiO2/TP achieves a prominent NH3 yield of 12394.3 mu g h(-1) cm(-2) and a high Faradaic efficiency of 88.4%. In addition, it exhibits excellent stability during long-time electrolysis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available