Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 808, Issue -, Pages 12-22Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2016.02.005
Keywords
Benzotriazole derivatives; NHC complexes; Metallamacrocycles; Catalytic activity
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Funding
- National Natural Science Foundation of China [21102117]
- Key Laboratory of Chemical Synthesis and Pollution Control of Sichuan Province [CSPC2014-4-1]
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The imidazolium salts [(N-alkyl-imidazolyl) methyl] benzotriazole hexafluorophosphate (L1H: alkyl = n-C4H9, L2H: alkyl = picoly, L3H: alkyl = 9-anthrylmethyl, L4H: alkyl = 1-naphthylmethyl) have been prepared. Mononuclear N-Heterocyclic carbene silver complexes: L1AgPF6 (1), L2AgPF6 (2), L3AgPF6 (3) were synthesized in DMSO. Transmetalation reactions afford the synthesis of the nickel(II) complex L2Ni(PF6)2 (4). Furthermore, L2H, L3H and L4H were treated with silver oxide in CH3CN to afford other complexes (5, 6 and 7). The complexes 5 and 6 formed 1D and 2D supramolecular chains by Ag-N bond and intermolecular p-p interactions, respectively, which were found that the carbene carbon atoms of NHCs are not coordinated to silver atom. However, in Complex 7, silver atoms selectly bind to nitrogen atoms of benzotriazoles and carbon atoms of imidazoles, which afford the dinuclear Ag metallamacrocycles. Complexes 1-7 were characterized by single crystal X-ray diffraction, NMR spectroscopy, elemental analysis and powder X-ray diffraction. The catalytic activity of NHC-Ni complex 4 for Suzuki-Miyaura cross-coupling was studied. (C) 2016 Elsevier B.V. All rights reserved.
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