4.6 Article

Shear Ablation Behavior and Mechanism of Liquid Silicone Rubber Composites at Different Ablation Angles and Distances

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 61, Issue 47, Pages 17306-17316

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.2c03003

Keywords

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Funding

  1. National Natural Science Foundation of China
  2. State Key Laboratory of Polymer Materials Engineering
  3. [51703137]
  4. [61409220207]
  5. [sklpme2019-2-02]

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The study examined the shear ablation behavior of liquid silicone rubber composites (LSRCs) using an oxyacetylene flame at different ablation angles and distances. Computational fluid dynamic simulations showed that ablation morphology varied significantly with angles, and shear ablation resulted in augmented ablation rates and asymmetric ablation craters. The acceleration was mainly attributed to powerful mechanical denudation induced by intense gas flow, disrupting continuity of the molten liquid layer and leading to quicker elimination of ablated boundary.
The shear ablation behavior of liquid silicone rubber composites (LSRCs) was examined using an oxyacetylene flame at different ablation angles and ablation distances. Computational fluid dynamic (CFD) simulations were conducted to determine the flow field of oxyacetylene flame at different ablation angles. Results indicated that the ablation morphology of LSRCs was significantly different at different ablation angles, and the centrally symmetrical structure of ablation pits under normal ablation turned to be an eccentric asymmetric distribution under shear ablation. Linear ablation rates were greatly augmented when the ablation distance was lower than the critical value where the shear force is dominant. The accelerated ablation rate and the asymmetric ablation craters were mainly attributed to the powerful mechanical denudation induced by an intense gas flow. The disruption of continuity of the molten liquid layer and further loss initiated a more rapid elimination of the ablated boundary. This work elaborated the influence of the ablation angle on the ablation behavior of LSRCs, which provided a reference for the design of an insulation material targeted for more serious service environments.

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