Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 805, Issue -, Pages 59-67Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2015.09.028
Keywords
Tridentate; Palladium; Seleno-ether; NMR spectroscopy; Suzuki; Catalytic efficiency
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Several tri-dentate ionic monochloro-palladium complexes of the type, [PdCl(N<^>E<^>N')][OTf] (3a-c, 3'a, 3'c) and [PdCl(C<^>Se<^>N')][OTf] (3d) (where, E = Se, Te; N' = 2-(3,5-dimethylpyrazol-1-yl)phenyl; N = ethylamine/N, N-dimethylethylamine/picolyl and C = 1-methyl-3-ethyl-2,3-dihydro-1H-imidazol carbene, respectively) were isolated from corresponding dichloro complexes (2aed, 2'a, 2'c) prepared by reacting PdCl2 with equimolar amount of seleno-ether ligands. Some of the representative ionic complexes were unambiguously analyzed by single crystal X-ray diffraction method, and employed for Suzuki-Miyaura carbon-carbon coupling reactions. The effect of subtle changes in ligands, such as variation in auxiliary donor group or chalcogen atom, on crystal structure and catalytic efficiency has been investigated. For the above mentioned studies, auxiliary donor groups of different donor strength such as amines/pyridyl (N-donor) and imidazole based carbene (C-donor) were introduced in seleno-ether ligands. (C) 2015 Elsevier B.V. All rights reserved.
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