Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 18, Pages 8268-8275Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01344
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Funding
- CNRS
- RADIOMI project (EU FP7-PEOPLE-ITN-RADIOMI)
- French Ministry of Research
- French Fluorine Network
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Trifluoromethylseleno substituent (CF3Se) is an emerging group, but its direct introduction onto organic molecules is still quite limited and mainly restricted to nucleophilic methods. Herein, we describe a new approach to easily and safely perform electrophilic trifluorome-thylselenolation starting from a simple and easily accessible reagent, namely, benzyltrifluoromethyl selenide. This strategy can be generalized to various fluoroalkylselanyl groups, even functionalized ones.
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