Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 3, Pages 946-955Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b02509
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Funding
- NSFC [21372085, 21203256]
- GNSF [10351064101000000, 2015A030306027]
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Copper(I)-catalyzed 5-sulfonation of quinolines via bidentate-chelation assistance has been developed. The reaction is compatible with a wide range of quinoline substrates and arylsulfonyl chlorides. Experimental and theoretical (DFT) investigation implicated that a single electron-transfer process is involved in this sulfonylation transformation.
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