Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 16, Pages 7282-7287Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00950
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Funding
- National Natural Science Foundation of China [U1204205, 21202078]
- Program for Innovative Research Team (in Science and Technology) in University of Henan Province [14IRTSTHNO08]
- Innovation Scientists and Technicians Troop Construction Projects of Henan Province [154100510015]
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A visible-light-induced C-3 selective trifluoroethylation of imidazoheterocycles using 1,1,1-trifluoro-2-iodoethane as trifluoroethyl radical sources was developed. The methodology enables the introduction of a trifluoroethyl group in a fast and efficient reaction under mild conditions with excellent regioselectivities and high functional group tolerance.
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