Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 10, Pages 4412-4420Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00655
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Funding
- National Natural Science Foundation of China [21572225]
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A strategy for achieving diastereodivergent azidations of enynes has been developed, employing azide transfer from the M-N-3 complex to alkyl radicals. Following this concept, the diastereoselectivity has been switched by modulating the transition metals and the ligands. The Mn(III)-mediated radical cyclization/azidation cascade of 1,7-enynes afforded trans-fused pyrrolo [3,4-c] quinolinones, whereas the Cu(II)/bipyridine system gave cis-products.
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