4.7 Article

Inherently Chiral Azonia[6]helicene-Modified β-Cyclodextrin: Synthesis, Characterization, and Chirality Sensing of Underivatized Amino Acids in Water

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 8, Pages 3430-3434

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00130

Keywords

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Funding

  1. National Natural Science Foundation of China [21372165, 21321061, 21402129, 21572142]
  2. State Key Laboratory of Polymer Materials Engineering [sklpme2014-2-06]
  3. Japan Society for the Promotion of Science [26620030, 26620061, 25620163, 24655025, 23350018]
  4. Mitsubishi Chemical Corporation Fund
  5. Sumitomo Foundation
  6. Shorai Foundation
  7. Kurata Foundation
  8. Tokuyama Foundation
  9. Iketani Foundation
  10. Grants-in-Aid for Scientific Research [16H06041, 15H01087, 15H03779, 26620030, 24655025, 26620061, 25620163, 15K13642] Funding Source: KAKEN

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The (P)- and (M)-3-azonia[6]helicenyl beta-cyclo-dextrins exhibit L/D selectivities of up to 12.4 and P/M preferences of up to 28.2 upon complexation with underivatized proteinogenic amino acids in aqueous solution at pH 7.3.

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