Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 1, Pages 126-134Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02257
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Funding
- National Natural Science Foundation of China [81220108025, 21472209, 91229204]
- Major Project of Chinese National Programs for Fundamental Research and Development [2015CB910304]
- National Basic Research Program of China [2012CB518005]
- National S&T Major Projects [2013ZX09507-001, 2014ZX09507002-001]
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An efficient palladium-catalyzed ortho-alkoxylation of N-benzoyl alpha-amino acid derivatives at room temperature has been explored. This novel transformation, using amino acids as directing groups, Pd(OAc)(2) as catalyst, alcohols as the alkoxylation reagents, and PhI(OAc)(2) as the oxidant, showed wide generality, good functional tolerance, and high monoselectivity and regioselectivity.
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