Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 16, Pages 7001-7007Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00234
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Funding
- National Natural Science Foundation of China [21421002, 21332010, 21272036]
- National Basic Research Program of China [2012CB21600]
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A convenient, visible light induced oxidifluoro-methylation of styrenes was developed. This protocol employs the readily prepared difluoromethyltriphenylphosphonium bromide as the difluoromethylating reagent and alcohols/water as the nucleophiles, affording difluoromethyl(CF2H)-containing alcohols and ethers in moderate to excellent yields.
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